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Nitrate is a polyatomic ion with the chemical formula NO − 3. Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. [1] Almost all inorganic nitrates are soluble in water. An example of an insoluble nitrate is bismuth oxynitrate.
The linear form of N 3 was discovered in 1956 by B. A. Thrush [4] by photolysis of hydrogen azide. [5] As a linear and symmetric molecule, it has D ∞h symmetry, with a nitrogen–nitrogen bond length averaging 1.8115 Å. The first excited electronic state, A 2 Σ u, is 4.56 eV above the ground state. [1]
In chemistry, azide (/ ˈ eɪ z aɪ d /, AY-zyd) is a linear, polyatomic anion with the formula N − 3 and structure − N=N + =N −. It is the conjugate base of hydrazoic acid HN 3. Organic azides are organic compounds with the formula RN 3, containing the azide functional group. [1] The dominant application of azides is as a propellant in ...
The 15 N: 14 N ratio is commonly used in stable isotope analysis in the fields of geochemistry, hydrology, paleoclimatology and paleoceanography, where it is called δ 15 N. [40] Of the thirteen other isotopes produced synthetically, ranging from 9 N to 23 N, 13 N has a half-life of ten minutes and the remaining isotopes have half-lives less ...
Many stoichiometric phases are usually present for most elements (e.g. MnN, Mn 6 N 5, Mn 3 N 2, Mn 2 N, Mn 4 N, and Mn x N for 9.2 < x < 25.3). They may be classified as "salt-like" (mostly ionic), covalent, "diamond-like", and metallic (or interstitial ), although this classification has limitations generally stemming from the continuity of ...
In chemistry, the pentazenium cation (also known as pentanitrogen) is a positively-charged polyatomic ion with the chemical formula N + 5 and structure N−N−N−N−N.Together with solid nitrogen polymers and the azide anion, it is one of only three poly-nitrogen species obtained in bulk quantities.
S 4 N 4 is also unstable with respect to the elements, but less so that the isostructural Se 4 N 4. Heating S 4 N 4 gives a polymer, and a variety of molecular sulfur nitride anions and cations are also known. Related to but distinct from nitride is pernitride diatomic anion (N 2− 2) and the azide triatomic anion (N 3 −).
In its most characteristic reaction, the solid decomposes explosively, releasing nitrogen gas: 2 AgN 3 (s) → 3 N 2 (g) + 2 Ag(s). The first step in this decomposition is the production of free electrons and azide radicals; thus the reaction rate is increased by the addition of semiconducting oxides. [4]