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  2. Exponent bias - Wikipedia

    en.wikipedia.org/wiki/Exponent_bias

    When interpreting the floating-point number, the bias is subtracted to retrieve the actual exponent. For a half-precision number, the exponent is stored in the range 1 .. 30 (0 and 31 have special meanings), and is interpreted by subtracting the bias for an 5-bit exponent (15) to get an exponent value in the range −14 .. +15.

  3. Glossary of chemistry terms - Wikipedia

    en.wikipedia.org/wiki/Glossary_of_chemistry_terms

    Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...

  4. Half-precision floating-point format - Wikipedia

    en.wikipedia.org/wiki/Half-precision_floating...

    Exponent bias = 01111 2 = 15 Thus, as defined by the offset binary representation, in order to get the true exponent the offset of 15 has to be subtracted from the stored exponent. The stored exponents 00000 2 and 11111 2 are interpreted specially.

  5. Reaction rate constant - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate_constant

    where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here ⁠ ⁠ is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...

  6. Pre-exponential factor - Wikipedia

    en.wikipedia.org/wiki/Pre-exponential_factor

    In chemical kinetics, the pre-exponential factor or A factor is the pre-exponential constant in the Arrhenius equation (equation shown below), an empirical relationship between temperature and rate coefficient. It is usually designated by A when determined from experiment, while Z is usually left for collision frequency. The pre-exponential ...

  7. Steric factor - Wikipedia

    en.wikipedia.org/wiki/Steric_factor

    Also called the probability factor, the steric factor is defined as the ratio between the experimental value of the rate constant and the one predicted by collision theory. It can also be defined as the ratio between the pre-exponential factor and the collision frequency, and it is most often less than unity.

  8. Fick's laws of diffusion - Wikipedia

    en.wikipedia.org/wiki/Fick's_laws_of_diffusion

    When the area of interest is the size of a molecule (specifically, a long cylindrical molecule such as DNA), the adsorption rate equation represents the collision frequency of two molecules in a diluted solution, with one molecule a specific side and the other no steric dependence, i.e., a molecule (random orientation) hit one side of the other ...

  9. IEEE 754-1985 - Wikipedia

    en.wikipedia.org/wiki/IEEE_754-1985

    In single precision, the bias is 127, so in this example the biased exponent is 124; in double precision, the bias is 1023, so the biased exponent in this example is 1020. fraction = .01000… 2 . IEEE 754 adds a bias to the exponent so that numbers can in many cases be compared conveniently by the same hardware that compares signed 2's ...

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