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HBr can be prepared by distillation of a solution of sodium bromide or potassium bromide with phosphoric acid or sulfuric acid: [14] KBr + H 2 SO 4 → KHSO 4 + HBr. Concentrated sulfuric acid is less effective because it oxidizes HBr to bromine: 2 HBr + H 2 SO 4 → Br 2 + SO 2 + 2 H 2 O. The acid may be prepared by: reaction of bromine with ...
The radical groups can then interact with HBr to produce a Br radical, which then reacts with the double bond. Since the bromine atom is relatively large, it is more likely to encounter and react with the least substituted carbon since this interaction produces less static interactions between the carbon and the bromine radical.
In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene. It proceeds by a free-radical chain ...
Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction of excited atomic oxygen with water. It is also an important radical formed in radiation chemistry, since it leads to the formation of hydrogen peroxide and oxygen, which can enhance corrosion and stress ...
Reaction inhibitors slow down a radical reaction and radical disproportionation is a competing reaction. Radical reactions occur frequently in the gas phase, are often initiated by light, are rarely acid or base catalyzed and are not dependent on polarity of the reaction medium. [2] Reactions are also similar whether in the gas phase or ...
In organic chemistry, free-radical addition is an addition reaction which involves free radicals. These reactions can happen due to the free radicals having an unpaired electron in their valence shell, making them highly reactive. [1] Radical additions are known for a variety of unsaturated substrates, both olefinic or aromatic and with or ...
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Most chemical reactions take more than one elementary step to complete, and a reactive intermediate is a high-energy, hence unstable, product that exists only in one of the intermediate steps. The series of steps together make a reaction mechanism .