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  2. Hydrogen bromide - Wikipedia

    en.wikipedia.org/wiki/Hydrogen_bromide

    HBr can be prepared by distillation of a solution of sodium bromide or potassium bromide with phosphoric acid or sulfuric acid: [14] KBr + H 2 SO 4 → KHSO 4 + HBr. Concentrated sulfuric acid is less effective because it oxidizes HBr to bromine: 2 HBr + H 2 SO 4 → Br 2 + SO 2 + 2 H 2 O. The acid may be prepared by: reaction of bromine with ...

  3. Free-radical halogenation - Wikipedia

    en.wikipedia.org/wiki/Free-radical_halogenation

    In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene. It proceeds by a free-radical chain ...

  4. Markovnikov's rule - Wikipedia

    en.wikipedia.org/wiki/Markovnikov's_rule

    The radical groups can then interact with HBr to produce a Br radical, which then reacts with the double bond. Since the bromine atom is relatively large, it is more likely to encounter and react with the least substituted carbon since this interaction produces less static interactions between the carbon and the bromine radical.

  5. Bromous acid - Wikipedia

    en.wikipedia.org/wiki/Bromous_acid

    A redox reaction of hypobromous acid (HBrO) can form bromous acid (HBrO 2) as its product: [citation needed] HBrO + H 2 O − 2e − → HBrO 2 + 2H + The disproportionation reaction of two equivalents hypobromous acid (HBrO) results in the formation of both bromous acid (HBrO 2) and hydrobromic acid (HBr): [citation needed] 2 HBrO → HBrO 2 + HBr

  6. Hydrobromic acid - Wikipedia

    en.wikipedia.org/wiki/Hydrobromic_acid

    Hydrobromic acid is an aqueous solution of hydrogen bromide.It is a strong acid formed by dissolving the diatomic molecule hydrogen bromide (HBr) in water. "Constant boiling" hydrobromic acid is an aqueous solution that distills at 124.3 °C (255.7 °F) and contains 47.6% HBr by mass, which is 8.77 mol/L. Hydrobromic acid is one of the strongest mineral acids known.

  7. Hydrohalogenation - Wikipedia

    en.wikipedia.org/wiki/Hydrohalogenation

    A hydrohalogenation reaction is the electrophilic addition of hydrogen halides like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes. [ 1 ] [ 2 ] [ 3 ] If the two carbon atoms at the double bond are linked to a different number of hydrogen atoms, the halogen is found preferentially at the carbon with fewer ...

  8. Reactive intermediate - Wikipedia

    en.wikipedia.org/wiki/Reactive_intermediate

    Most chemical reactions take more than one elementary step to complete, and a reactive intermediate is a high-energy, hence unstable, product that exists only in one of the intermediate steps. The series of steps together make a reaction mechanism .

  9. Free-radical addition - Wikipedia

    en.wikipedia.org/wiki/Free-radical_addition

    Chain propagation: A radical reacts with a non-radical to produce a new radical species; Chain termination: Two radicals react with each other to create a non-radical species; In a free-radical addition, there are two chain propagation steps. In one, the adding radical attaches to a multiply-bonded precursor to give a radical with lesser bond ...