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Idealized structure of lignin from a softwood. Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. [1] Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily.
Lignin confers structural integrity to plants. Lignin is so heterogeneous and so recalcitrant that its value is almost exclusively measured as a fuel. hemicellulose is composed of branched polysaccharides. A particular problem is that hemicellulose is covalently linked to lignin, usually through ferulic acid component of the
Biopolymers can be sustainable, carbon neutral and are always renewable, because they are made from plant or animal materials which can be grown indefinitely. Since these materials come from agricultural crops , their use could create a sustainable industry.
The term "lignin characterization" (or "lignin analysis") refers to a group of activities within lignin research aiming at describing the characteristics of a lignin by determination of its most important properties. [1] Most often, this term is used to describe the characterization of technical lignins by means of chemical or thermo-chemical ...
After cellulose, lignin is the second most abundant biopolymer and is one of the primary structural components of most plants. It contains subunits derived from p -coumaryl alcohol , coniferyl alcohol , and sinapyl alcohol , [ 15 ] and is unusual among biomolecules in that it is racemic .
The major constituents of natural fibers (lignocelluloses) are cellulose, hemicellulose, lignin, pectin and ash. The percentage of each component varies for each different type of fiber, however, generally, are around 60-80% cellulose, 5–20% lignin, and 20% of moisture, besides hemicellulose and a small percent of residual chemical components.
[59] [60] The environmental impact of bioplastics is often debated, as there are many different metrics for "greenness" (e.g., water use, energy use, deforestation, biodegradation, etc.). [ 61 ] [ 62 ] [ 63 ] Hence bioplastic environmental impacts are categorized into nonrenewable energy use, climate change , eutrophication and acidification ...
The major combustible component of non-food energy crops is cellulose, with lignin second. Non-food energy crops produce more usable energy than edible energy crops (which have a large starch component), but still compete with food crops for agricultural land and water resources. [ 74 ]
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