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Ruthenium(IV) oxide is the inorganic compound with the formula Ru O 2. This black solid is the most common oxide of ruthenium . It is widely used as an electrocatalyst for producing chlorine, chlorine oxides, and O 2 . [ 1 ]
Ruthenium can be oxidized to ruthenium(IV) oxide (RuO 2, oxidation state +4), which can, in turn, be oxidized by sodium metaperiodate to the volatile yellow tetrahedral ruthenium tetroxide, RuO 4, an aggressive, strong oxidizing agent with structure and properties analogous to osmium tetroxide.
Ruthenium can be oxidized to ruthenium(IV) oxide (RuO 2, oxidation state +4), which can, in turn, be oxidized by sodium metaperiodate to the volatile yellow tetrahedral ruthenium tetroxide, RuO 4, an aggressive, strong oxidizing agent with structure and properties analogous to osmium tetroxide.
Ruthenium oxide may refer to either of the following: Ruthenium(IV) oxide, RuO 2; Ruthenium(VIII) oxide, RuO 4 This page was last edited on 13 May 2022 ...
Phase behavior Triple point? K (? °C), ? Pa Critical point? K (? °C), ? Pa Std enthalpy change of fusionΔ fus H o? kJ/mol Std entropy change of fusionΔ fus S oJ/(mol·K)
Perruthenate can be produced as the sodium [2] or potassium [3] salt by reduction of ruthenium tetroxide with alkaline hydroxide: 4 RuO 4 + 4 KOH → 4 KRuO 4 + 2 H 2 O + O 2. Both the concentration and temperature of the reduction must be controlled to avoid further reduction to ruthenate: [4] 4 KRuO 4 + 4 KOH → 4 K 2 RuO 4 + 2 H 2 O + O 2
Most definitions of the term 'refractory metals' list the extraordinarily high melting point as a key requirement for inclusion. By one definition, a melting point above 4,000 °F (2,200 °C) is necessary to qualify, which includes iridium, osmium, niobium, molybdenum, tantalum, tungsten, rhenium, rhodium, ruthenium and hafnium. [2]
This toxic compound is formed when powdered osmium is exposed to air. It is a very volatile, water-soluble, pale yellow, crystalline solid with a strong smell. Osmium powder has the characteristic smell of osmium tetroxide. [31] Osmium tetroxide forms red osmates OsO 4 (OH) 2− 2 upon reaction with a base. With ammonia, it forms the nitrido ...
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