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Sodium hydroxide, also known as lye and caustic soda, [1] [2] is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na + and hydroxide anions OH −. Sodium hydroxide is a highly corrosive base and alkali that decomposes lipids and proteins at ambient temperatures and may cause severe ...
A calculated titration curve of oxalic acid titrated with a solution of sodium hydroxide. The experimental determination of pK a values is commonly performed by means of titrations, in a medium of high ionic strength and at constant temperature. [58] A typical procedure would be as follows.
The hydroxide ion by itself is not a strong enough base, but it can be converted in one by adding sodium hydroxide to ethanol. OH − + EtOH ⇌ EtO − + H 2 O. to produce the ethoxide ion. The pK a for self-dissociation of ethanol is about 16, so the alkoxide ion is a strong enough base. [49]
An early method for producing phenol involved the base hydrolysis of sodium benzenesulfonate, which can be generated readily from benzene. [15] C 6 H 5 SO 3 Na + NaOH → C 6 H 5 OH + Na 2 SO 3. The conditions for this reaction are harsh, however, requiring 'fused alkali' or molten sodium hydroxide at 350 °C for benzenesulfonic acid itself. [16]
As the name suggests, a non-nucleophilic base is a sterically hindered organic base that is a poor nucleophile.Normal bases are also nucleophiles, but often chemists seek the proton-removing ability of a base without any other functions.
Potassium hydroxide is preferred over sodium hydroxide because its solutions are more conductive. [20] The nickel–metal hydride batteries in the Toyota Prius use a mixture of potassium hydroxide and sodium hydroxide. [21] Nickel–iron batteries also use potassium hydroxide electrolyte.
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