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In heterogeneous electron transfer, an electron moves between a chemical species present in solution and the surface of a solid such as a semi-conducting material or an electrode. Theories addressing heterogeneous electron transfer have applications in electrochemistry and the design of solar cells.
In theoretical chemistry, Marcus theory is a theory originally developed by Rudolph A. Marcus, starting in 1956, to explain the rates of electron transfer reactions – the rate at which an electron can move or jump from one chemical species (called the electron donor) to another (called the electron acceptor). [1]
Photoinduced electron transfer (PET) is an excited state electron transfer process by which an excited electron is transferred from donor to acceptor. [ 1 ] [ 2 ] Due to PET a charge separation is generated, i.e. , redox reaction takes place in excited state (this phenomenon is not observed in Dexter electron transfer ).
An uncoupler or uncoupling agent is a molecule that disrupts oxidative phosphorylation in prokaryotes and mitochondria or photophosphorylation in chloroplasts and cyanobacteria by dissociating the reactions of ATP synthesis from the electron transport chain.
An electron transport chain (ETC [1]) is a series of protein complexes and other molecules which transfer electrons from electron donors to electron acceptors via redox reactions (both reduction and oxidation occurring simultaneously) and couples this electron transfer with the transfer of protons (H + ions) across a membrane.
The RTE is a differential equation describing radiance (, ^,).It can be derived via conservation of energy.Briefly, the RTE states that a beam of light loses energy through divergence and extinction (including both absorption and scattering away from the beam) and gains energy from light sources in the medium and scattering directed towards the beam.
Outer sphere electron transfer can occur between chemical species that are identical except for their oxidation state. [4] This process is termed self-exchange. An example is the degenerate reaction between the tetrahedral ions permanganate and manganate:
A phylloquinone, sometimes called vitamin K 1, [16] is the next early electron acceptor in PSI. It oxidizes A 1 in order to receive the electron and in turn is re-oxidized by F x, from which the electron is passed to F b and F a. [16] [17] The reduction of F x appears to be the rate-limiting step. [15]