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Diazomethane conjugated pi-system. In theoretical chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in a molecule, which in general lowers the overall energy of the molecule and increases stability. It is conventionally represented as having alternating single and multiple bonds.
A leuco dye (from the Greek λευκό leuko: white ) is a dye which can switch between two chemical forms, one of which is colorless. Reversible transformations can be caused by heat, light or pH, resulting in examples of thermochromism, photochromism and halochromism, respectively. Irreversible transformations typically involve reduction or ...
Cross-conjugation. Cross-conjugation is a special type of conjugation in a molecule, when in a set of three pi bonds only two pi bonds interact with each other by conjugation, while the third one is excluded from interaction. [1][2] Whereas a normal conjugated system such as a polyene typically has alternating single and double bonds along ...
The best-known example is benzene (C 6 H 6) with a conjugated system of six π electrons, which equals 4n + 2 for n = 1. The molecule undergoes substitution reactions which preserve the six π electron system rather than addition reactions which would destroy it. The stability of this π electron system is referred to as aromaticity. Still, in ...
e. In linguistics, conjugation (/ ˌkɒndʒʊˈɡeɪʃən / [1][2]) is the creation of derived forms of a verb from its principal parts by inflection (alteration of form according to rules of grammar). For instance, the verb break can be conjugated to form the words break, breaks, and broke. While English has a relatively simple conjugation ...
A cyclic compound (or ring compound) is a term for a compound in the field of chemistry in which one or more series of atoms in the compound is connected to form a ring. Rings may vary in size from three to many atoms, and include examples where all the atoms are carbon (i.e., are carbocycles), none of the atoms are carbon (inorganic cyclic ...
β-carotene is a conjugated polyene Conjugated polyene systems can be modeled using particle in a box. [ 12 ] The conjugated system of electrons can be modeled as a one dimensional box with length equal to the total bond distance from one terminus of the polyene to the other.
Simple aromatic rings, also known as simple arenes or simple aromatics, are aromatic organic compounds that consist only of a conjugated planar ring system. Many simple aromatic rings have trivial names. They are usually found as substructures of more complex molecules (" substituted aromatics"). Typical simple aromatic compounds are benzene ...