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By contrast, an extensive property or extensive quantity is one whose magnitude is additive for subsystems. [4] Examples include mass, volume and Gibbs energy. [5] Not all properties of matter fall into these two categories. For example, the square root of the volume is neither intensive nor extensive. [1]
The final column lists some special properties that some of the quantities have, such as their scaling behavior (i.e. whether the quantity is intensive or extensive), their transformation properties (i.e. whether the quantity is a scalar, vector, matrix or tensor), and whether the quantity is conserved.
In quantum chemistry, size consistency and size extensivity are concepts relating to how the behaviour of quantum-chemistry calculations changes with the system size. Size consistency (or strict separability) is a property that guarantees the consistency of the energy behaviour when interaction between the involved molecular subsystems is nullified (for example, by distance).
An intensive property does not depend on the size or extent of the system, nor on the amount of matter in the object, while an extensive property shows an additive relationship. These classifications are in general only valid in cases when smaller subdivisions of the sample do not interact in some physical or chemical process when combined.
They are called intensive variables or extensive variables according to how they change when the size of the system changes. The properties of the system can be described by an equation of state which specifies the relationship between these variables. State may be thought of as the instantaneous quantitative description of a system with a set ...
The magnitude of an intensive quantity does not depend on the size, or extent, of the object or system of which the quantity is a property, whereas magnitudes of an extensive quantity are additive for parts of an entity or subsystems. Thus, magnitude does depend on the extent of the entity or system in the case of extensive quantity.
In science and engineering, an intrinsic property is a property of a specified subject that exists itself or within the subject. An extrinsic property is not essential or inherent to the subject that is being characterized.
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...