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Henderson–Hasselbalch equation. In chemistry and biochemistry, the Henderson–Hasselbalch equation relates the pH of a chemical solution of a weak acid to the numerical value of the acid dissociation constant, Ka, of acid and the ratio of the concentrations, of the acid and its conjugate base in an equilibrium. [1]
v. t. e. In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction. known as dissociation in the context of acid–base reactions. The chemical species HA is an ...
Dissociation constant. In chemistry, biochemistry, and pharmacology, a dissociation constant (KD) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its ...
It is the quantity of base (usually potassium hydroxide (KOH)), expressed as milligrams of KOH required to neutralize the acidic constituents in 1 gram of a sample. [1][2][3][4] The acid value measures the acidity of water-insoluble substances like oils, fats, waxes and resins, which do not have a pH value. The acid number is a measure of the ...
pH values can be measured in non-aqueous solutions, but they are based on a different scale from aqueous pH values, because the standard states used for calculating hydrogen ion concentrations are different. The hydrogen ion activity, a H +, is defined [21] [22] as:
Gran plot. A Gran plot (also known as Gran titration or the Gran method) is a common means of standardizing a titrate or titrant by estimating the equivalence volume or end point in a strong acid -strong base titration or in a potentiometric titration. Such plots have been also used to calibrate glass electrodes, to estimate the carbonate ...
Speciation of ions refers to the changing concentration of varying forms of an ion as the pH of the solution changes. [ 1] The ratio of acid, AH and conjugate base, A −, concentrations varies as the difference between the pH and the p Ka varies, in accordance with the Henderson-Hasselbalch equation. The pH of a solution of a monoprotic weak ...
Acid strength is the tendency of an acid, symbolised by the chemical formula , to dissociate into a proton, , and an anion, . The dissociation or ionization of a strong acid in solution is effectively complete, except in its most concentrated solutions. Examples of strong acids are hydrochloric acid , perchloric acid , nitric acid and sulfuric ...