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Monoisotopic mass (M mi) is one of several types of molecular masses used in mass spectrometry. The theoretical monoisotopic mass of a molecule is computed by taking the sum of the accurate masses (including mass defect ) of the most abundant naturally occurring stable isotope of each atom in the molecule.
The monoisotopic mass is the sum of the masses of the atoms in a molecule using the unbound, ground-state, rest mass of the principal (most abundant) isotope for each element. [12] [5] The monoisotopic mass of a molecule or ion is the exact mass obtained using the principal isotopes. Monoisotopic mass is typically expressed in daltons.
In mass spectrometry, the molecular mass of a small molecule is usually reported as the monoisotopic mass: that is, the mass of the molecule containing only the most common isotope of each element. This also differs subtly from the molecular mass in that the choice of isotopes is defined and thus is a single specific molecular mass out of the ...
Only fluorine-19 is stable and naturally occurring in more than trace quantities; therefore, fluorine is a monoisotopic and mononuclidic element. The longest-lived radioisotope is 18 F; it has a half-life of 109.734(8) min. All other fluorine isotopes have half-lives of less than a minute, and most of those less than a second.
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a mass spectrum, a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures.
Monoisotopic mass is the sum of the masses of the atoms in a molecule using the most abundant isotope for each element; Monoisotopic element is one of the 26 chemical ...
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Fluorine is monoisotopic, so any mass differences between UF 6 molecules are due to the presence of 235 U or 238 U, enabling uranium enrichment via gaseous diffusion or gas centrifuge. [5] [65] About 6,000 metric tons per year go into producing the inert dielectric SF