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  2. Enthalpy change of solution - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_change_of_solution

    The temperature of the solution eventually decreases to match that of the surroundings. The equilibrium, between the gas as a separate phase and the gas in solution, will by Le Châtelier's principle shift to favour the gas going into solution as the temperature is decreased (decreasing the temperature increases the solubility of a gas).

  3. Thermal decomposition - Wikipedia

    en.wikipedia.org/wiki/Thermal_decomposition

    Thermal decomposition, or thermolysis, is a chemical decomposition of a substance caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing

  4. Thermodynamics of micellization - Wikipedia

    en.wikipedia.org/wiki/Thermodynamics_of_micelliz...

    The Krafft temperature of a surfactant is the lowest temperature required for micellization to take place. There are many parameters that affect the CMC. The interaction between the hydrophilic heads and the hydrophobic tails play a part, as well as the concentration of salt within the solution and surfactants.

  5. Water splitting - Wikipedia

    en.wikipedia.org/wiki/Water_splitting

    At the very high temperature of 3,000 °C (3,270 K; 5,430 °F) more than half of the water molecules are decomposed. At ambient temperatures only one molecule in 100 trillion dissociates by the effect of heat. [15] The high temperature requirements and material constraints have limited the applications of the thermal decomposition approach.

  6. Thermodynamic temperature - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_temperature

    Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...

  7. Thermophoresis - Wikipedia

    en.wikipedia.org/wiki/Thermophoresis

    Thermophoresis (also thermomigration, thermodiffusion, the Soret effect, or the Ludwig–Soret effect) is a phenomenon observed in mixtures of mobile particles where the different particle types exhibit different responses to the force of a temperature gradient. This phenomenon tends to move light molecules to hot regions and heavy molecules to ...

  8. Hydrophobic effect - Wikipedia

    en.wikipedia.org/wiki/Hydrophobic_effect

    The hydrophobic effect is the observed tendency of nonpolar substances to aggregate in an aqueous solution and to be excluded by water. [ 1 ] [ 2 ] The word hydrophobic literally means "water-fearing", and it describes the segregation of water and nonpolar substances, which maximizes the entropy of water and minimizes the area of contact ...

  9. Freezing-point depression - Wikipedia

    en.wikipedia.org/wiki/Freezing-point_depression

    In the above equation, T F is the normal freezing point of the pure solvent (273 K for water, for example); a liq is the activity of the solvent in the solution (water activity for aqueous solution); ΔH fus T F is the enthalpy change of fusion of the pure solvent at T F, which is 333.6 J/g for water at 273 K; ΔC fus p is the difference ...