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The mevalonate pathway of eukaryotes, archaea, and eubacteria all begin the same way. The sole carbon feed stock of the pathway is acetyl-CoA. The first step condenses two acetyl-CoA molecules to yield acetoacetyl-CoA. This is followed by a second condensation to form HMG-CoA (3-hydroxy-3- methyl-glutaryl-CoA).
Electron donors (e.g. nucleophiles, Lewis bases) for example dimethylsulfide and dimethylsulfoxide are believed to stabilize the carbocation. The addition of salt for example a tetraalkylammonium salt, prevents dissociation of the ion pair that is the propagating reactive site. Ion dissociation into free ions lead to non-living polymerization.
The two reactions are named according tho their rate law, with S N 1 having a first-order rate law, and S N 2 having a second-order. [2] S N 1 reaction mechanism occurring through two steps. The S N 1 mechanism has two steps. In the first step, the leaving group departs, forming a carbocation (C +). In the second step, the nucleophilic reagent ...
Matplotlib (portmanteau of MATLAB, plot, and library [3]) is a plotting library for the Python programming language and its numerical mathematics extension NumPy.It provides an object-oriented API for embedding plots into applications using general-purpose GUI toolkits like Tkinter, wxPython, Qt, or GTK.
Although the initial carbocation is already tertiary, the oxygen can stabilize the positive charge much more favorably due to the complete octet configuration at all centers. It can also be seen as the -OH's lone pairs pushing an alkyl group off as seen in the asymmetrical pinacol example.
Livegap Charts creates line, bar, spider, polar-area and pie charts, and can export them as images without needing to download any tools. Veusz is a free scientific graphing tool that can produce 2D and 3D plots. Users can use it as a module in Python. GeoGebra is open-source graphing calculator and is freely available for non-commercial users.
In simplest terms, a potential energy surface or PES is a mathematical or graphical representation of the relation between energy of a molecule and its geometry. The methods for describing the potential energy are broken down into a classical mechanics interpretation (molecular mechanics) and a quantum mechanical interpretation.
E1 and E2 are two different mechanisms for elimination reactions, and E1 involves a carbocation intermediate. In E1, a leaving group detaches from a carbon to form a carbocation reaction intermediate. Then, a solvent removes a proton, but the electrons used to form the proton bond form a pi bond, as shown in the pictured reaction on the right. [4]