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Enantiotopic groups are identical and indistinguishable except in chiral environments. For instance, the CH 2 hydrogens in ethanol (CH 3 CH 2 OH) are normally enantiotopic, but can be made different (diastereotopic) if combined with a chiral center, for instance by conversion to an ester of a chiral carboxylic acid such as lactic acid, or if coordinated to a chiral metal center, or if ...
Recall that a point can be considered a sterocenter with a minimum of three attachment points; stereocenters can be either sp 3 or sp 2 hybridized, as long as the interchanging any two different groups creates a new stereoisomer. This means that although all chirality centers are stereocenters, not every stereocenter is a chirality center.
That is, the groups hanging off the chain at the α-carbon are what give amino acids their diversity. These groups give the α-carbon its stereogenic properties for every amino acid except for glycine. Therefore, the α-carbon is a stereocenter for every amino acid except glycine. Glycine also does not have a β-carbon, while every other amino ...
In stereochemistry, an asymmetric carbon is a carbon atom that is bonded to four different types of atoms or groups of atoms. [1] [2] The four atoms and/or groups attached to the carbon atom can be arranged in space in two different ways that are mirror images of each other, and which lead to so-called left-handed and right-handed versions (stereoisomers) of the same molecule.
The isopropenyl group has priority 1 (carbon atoms only), and for the two remaining carbon atoms, priority is decided with the carbon atoms two bonds removed from the stereocenter, one part of the keto group (O, O, C, priority number 2) and one part of an alkene (C, C, H, priority number 3).
John Conway uses a variation of the Schoenflies notation, based on the groups' quaternion algebraic structure, labeled by one or two upper case letters, and whole number subscripts. The group order is defined as the subscript, unless the order is doubled for symbols with a plus or minus, "±", prefix, which implies a central inversion. [3]
This article summarizes the classes of discrete symmetry groups of the Euclidean plane. The symmetry groups are named here by three naming schemes: International notation, orbifold notation, and Coxeter notation. There are three kinds of symmetry groups of the plane: 2 families of rosette groups – 2D point groups; 7 frieze groups – 2D line ...
When the single bond between the two centres is free to rotate, cis/trans descriptors become invalid. Two widely accepted prefixes used to distinguish diastereomers on sp³-hybridised bonds in an open-chain molecule are syn and anti. Masamune proposed the descriptors which work even if the groups are not attached to adjacent carbon atoms.