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Osmotic pressure is the minimum pressure which needs to be applied to a solution to prevent the inward flow of its pure solvent across a semipermeable membrane. [1] It is also defined as the measure of the tendency of a solution to take in its pure solvent by osmosis .
where is the chemical potential of the pure solvent and is the chemical potential of the solvent in a solution, M A is its molar mass, x A its mole fraction, R the gas constant and T the temperature in Kelvin. [1] The latter osmotic coefficient is sometimes called the rational osmotic coefficient. The values for the two definitions are ...
Osmotic pressure is a measure of the tendency of water to move into one solution from another by osmosis. [1] The higher the osmotic pressure of a solution, the more water tends to move into it. Pressure must be exerted on the hypertonic side of a selectively permeable membrane to prevent diffusion of water by osmosis from the side containing ...
For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1. For most ionic compounds dissolved in water, the van 't Hoff factor is equal to the number of discrete ions in a formula unit of the substance. This is true for ideal solutions only, as occasionally ion pairing occurs in solution. At a given instant a small ...
The process stops and equilibrium is attained when the pressure difference equals the osmotic pressure. Two laws governing the osmotic pressure of a dilute solution were discovered by the German botanist W. F. P. Pfeffer and the Dutch chemist J. H. van’t Hoff: The osmotic pressure of a dilute solution at constant temperature is directly ...
Thus, for every 1 mole of NaCl in solution, there are 2 osmoles of solute particles (i.e., a 1 mol/L NaCl solution is a 2 osmol/L NaCl solution). Both sodium and chloride ions affect the osmotic pressure of the solution. [2] [Note: NaCl does not dissociate completely in water at standard temperature and pressure, so the solution will be ...
Osmolarity is affected by changes in water content, as well as temperature and pressure. In contrast, osmolality is independent of temperature and pressure. For a given solution, osmolarity is slightly less than osmolality, because the total solvent weight (the divisor used for osmolality) excludes the weight of any solutes, whereas the total ...
The freezing point depression osmometer is an osmometer that is used in determining a solution's osmotic concentration as its osmotically active aspects depress its freezing point. In the past, freezing point osmometry has been used to assess the osmotic strength of colloids and solutions. The osmometer uses the solution's freezing point ...