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log 10 of Acetonitrile vapor pressure. Uses formula log e P m m H g = {\displaystyle \scriptstyle \log _{e}P_{mmHg}=} log e ( 760 101.325 ) − 3.881710 log e ( T + 273.15 ) − 4999.618 T + 273.15 + 41.05901 + 3.515956 × 10 − 06 ( T + 273.15 ) 2 {\displaystyle \scriptstyle \log _{e}({\frac {760}{101.325}})-3.881710\log _{e}(T+ ...
2.79 6.55 –20.2 Diethyl ether: 0.713 34.5 2.16 –116.3 –1.79 K b & K f [1] Methanol [4] 0.79 64.7 Ethanol: 0.78 78.4 1.22 –114.6 –1.99 K b [2] Ethylene bromide: 2.18 133 6.43 9.974 –12.5 K b & K f [1] Ethylene glycol: 1.11 197.3 2.26 −12.9 –3.11 K b & K f [1] Formic acid: 101.0 2.4 8.0 –2.77 K b & K f [1] Naphthalene: 217.9 78. ...
Polar aprotic solvents: acetone (CH 3) 2 CO 56.1 °C 21.8 0.785 g/cm 3: 2.91 reacts with strong acids and bases acetonitrile : CH 3 CN 82 °C 38.3 0.776 g/cm 3: 3.20 reacts with strong acids and bases dichloromethane: CH 2 Cl 2: 39.6 °C 9.08 1.327 g/cm 3: 1.6 low boiling point dimethylacetamide (CH 3) 2 NCOCH 3: 165 °C 37.8 0.94 g/cm 3: 3.72 ...
Acetonitrile is used mainly as a solvent in the purification of butadiene in refineries. Specifically, acetonitrile is fed into the top of a distillation column filled with hydrocarbons including butadiene, and as the acetonitrile falls down through the column, it absorbs the butadiene which is then sent from the bottom of the tower to a second separating tower.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
Here is a similar formula from the 67th edition of the CRC handbook. Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures:
The dipoles do not cancel out, resulting in a net dipole. The dipole moment of water depends on its state. In the gas phase the dipole moment is ≈ 1.86 debye (D), [11] whereas liquid water (≈ 2.95 D) [12] and ice (≈ 3.09 D) [13] are higher due to differing hydrogen-bonded environments.