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Manganese(II) oxide is an inorganic compound with chemical formula MnO. [2] It forms green crystals. The compound is produced on a large scale as a component of fertilizers and food additives .
Manganese may also form mixed oxides with other metals : Bixbyite, (Fe III,Mn III) 2 O 3, a manganese(III) iron(III) oxide mineral; Jacobsite, Mn II Fe III 2 O 4, a manganese(II) iron(III) oxide mineral; Columbite, (Fe II,Mn II)Nb 2 O 6, a niobate of iron(II) and manganese(II) Tantalite, (Fe II,Mn II)Ta 2 O 6, a tantalum(V) mineral group close ...
Manganese dioxide decomposes above about 530 °C to manganese(III) oxide and oxygen. At temperatures close to 1000 °C, the mixed-valence compound Mn 3 O 4 forms. Higher temperatures give MnO, which is reduced only with difficulty. [11] Hot concentrated sulfuric acid reduces MnO 2 to manganese(II) sulfate: [4] 2 MnO 2 + 2 H 2 SO 4 → 2 MnSO 4 ...
Manganese(IV) oxide was used in the original type of dry cell battery as an electron acceptor from zinc, and is the blackish material in carbon–zinc type flashlight cells. The manganese dioxide is reduced to the manganese oxide-hydroxide MnO(OH) during discharging, preventing the formation of hydrogen at the anode of the battery. [82]
Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO · Mn 2 O 3 . Mn 3 O 4 is found in nature as the mineral hausmannite .
Hausmannite is a complex oxide, or a mixed oxide, of manganese containing both di-and tri-valent manganese. Its chemical formula can be represented as Mn II Mn III 2 O 4, or more simply noted as MnO·Mn 2 O 3, or Mn 3 O 4, as commonly done for magnetite (Fe 3 O 4), the corresponding iron oxide. It belongs to the spinel group and forms ...
In the solid state below 159 °C, manganocene adopts a polymeric structure with every manganese atom coordinated by three cyclopentadienyl ligands, two of which are bridging ligands. Above 159 °C, the solid changes color from amber to pink and the polymer converts to the structure of a normal sandwich complex, i.e., the molecule Mn(η 5-C 5 H ...
Organomanganese chemistry is the chemistry of organometallic compounds containing a carbon to manganese chemical bond.In a 2009 review, Cahiez et al. argued that as manganese is cheap and benign (only iron performs better in these aspects), organomanganese compounds have potential as chemical reagents, although currently they are not widely used as such despite extensive research.