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The atmospheric pressure is roughly equal to the sum of partial pressures of constituent gases – oxygen, nitrogen, argon, water vapor, carbon dioxide, etc.. In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. [1]
pCO2, pCO2, or is the partial pressure of carbon dioxide (CO 2), often used in reference to blood but also used in meteorology, climate science, oceanography, and limnology to describe the fractional pressure of CO 2 as a function of its concentration in gas or dissolved phases. The units of p CO 2 are mmHg, atm, torr, Pa, or any other standard ...
The concentrations of carbon dioxide in the atmosphere are expressed as parts per million by volume (abbreviated as ppmv, or ppm(v), or just ppm). To convert from the usual ppmv units to ppm mass (abbreviated as ppmm, or ppm(m)), multiply by the ratio of the molar mass of CO 2 to that of air, i.e. times 1.52 (44.01 divided by 28.96).
An illustration of Dalton's law using the gases of air at sea level. Dalton's law (also called Dalton's law of partial pressures) states that in a mixture of non-reacting gases, the total pressure exerted is equal to the sum of the partial pressures of the individual gases. [1] This empirical law was observed by John Dalton in 1801 and ...
Correcting concentrations for altitude. Air pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m 3, μg/m 3, etc.) at sea level will decrease with increasing altitude. The concentration decrease is directly proportional to the pressure decrease with increasing altitude.
Fugacity. In chemical thermodynamics, the fugacity of a real gas is an effective partial pressure which replaces the mechanical partial pressure in an accurate computation of chemical equilibrium. It is equal to the pressure of an ideal gas which has the same temperature and molar Gibbs free energy as the real gas. [1]
Amagat's law states that the extensive volume V = Nv of a gas mixture is equal to the sum of volumes Vi of the K component gases, if the temperature T and the pressure p remain the same: [1][2] This is the experimental expression of volume as an extensive quantity. According to Amagat's law of partial volume, the total volume of a non-reacting ...
Wind speed conversion factors. Meteorological data includes wind speeds which may be expressed as statute miles per hour, knots, or meters per second. Here are the conversion factors for those various expressions of wind speed: 1 m/s = 2.237 statute mile/h = 1.944 knots. 1 knot = 1.151 statute mile/h = 0.514 m/s.