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Sphalerite, the more common polymorph of zinc sulfide Wurtzite, the less common polymorph of zinc sulfide. ZnS exists in two main crystalline forms. This dualism is an example of polymorphism. In each form, the coordination geometry at Zn and S is tetrahedral. The more stable cubic form is known also as zinc blende or sphalerite.
Sphalerite has been found as a pseudomorph, taking the crystal structure of galena, tetrahedrite, barite and calcite. [ 13 ] [ 15 ] Sphalerite can have Spinel Law twins, where the twin axis is [111]. The chemical formula of sphalerite is (Zn,Fe)S ; the iron content generally increases with increasing formation temperature and can reach up to 40 ...
This is also known as the sphalerite structure or the Structurbericht designation B3. Pages in category "Zincblende crystal structure" The following 36 pages are in this category, out of 36 total.
Stibnite Realgar. The sulphide minerals are a class of minerals containing sulphide (S 2−) or disulphide (S 2− 2) as the major anion.Some sulfide minerals are economically important as metal ores.
Its crystal structure is called the wurtzite crystal structure, to which it lends its name. This structure is a member of the hexagonal crystal system and consists of tetrahedrally coordinated zinc and sulfur atoms that are stacked in an ABABABABAB pattern. The unit cell parameters of wurtzite are (-2H polytype): [7] a = b = 3.81 Å = 381 pm; c ...
The sphalerite ore found here was presumably converted to zinc oxide via roasting, although no archaeological evidence of this has been found. Smelting is thought to have been done in sealed cylindrical clay retorts which were packed with a mixture of roasted ore, dolomite , and an organic material, perhaps cow dung , and then placed vertically ...
Three crystalline forms of CdSe are known which follow the structures of: wurtzite (hexagonal), sphalerite (cubic) and rock-salt (cubic). The sphalerite CdSe structure is unstable and converts to the wurtzite form upon moderate heating. The transition starts at about 130 °C, and at 700 °C it completes within a day.
Coordination number (CN) is the number of nearest neighbors of a central atom in the structure. [1] Each sphere in a cP lattice has coordination number 6, in a cI lattice 8, and in a cF lattice 12. Atomic packing factor (APF) is the fraction of volume that is occupied by atoms.