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A space-filling model of the diatomic molecule dinitrogen, N 2. Diatomic molecules (from Greek di- 'two') are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen (H 2) or oxygen (O 2), then it is said to be homonuclear.
For a diatomic gas, often 5 degrees of freedom are assumed to contribute at room temperature since each molecule has 3 translational and 2 rotational degrees of freedom, and the single vibrational degree of freedom is often not included since vibrations are often not thermally active except at high temperatures, as predicted by quantum ...
Molecules, such as oxygen (O 2), have more degrees of freedom than single spherical atoms: they undergo rotational and vibrational motions as well as translations. Heating results in an increase of temperature due to an increase in the average translational kinetic energy of the molecules.
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...
Only at temperatures well above temperatures in the troposphere and stratosphere do some molecules have enough energy to activate the vibrational modes of N 2 and O 2. The specific heat at constant volume, c v, increases slowly toward (7/2) R as temperature increases above T = 400 K, where c v is 1.3% above (5/2) R d = 717.5 J/(K kg).
The mathematical similarities between the expressions for shear viscocity, thermal conductivity and diffusion coefficient of the ideal (dilute) gas is not a coincidence; It is a direct result of the Onsager reciprocal relations (i.e. the detailed balance of the reversible dynamics of the particles), when applied to the convection (matter flow ...
The following is a table of some constant-pressure molar heat capacities c P,m of various diatomic gases at standard temperature (25 °C = 298 K), at 500 °C, and at 5000 °C, and the apparent number of degrees of freedom f * estimated by the formula f * = 2c P,m /R − 2:
Hydrogen is commonly used in power stations as a coolant in generators due to a number of favorable properties that are a direct result of its light diatomic molecules. These include low density, low viscosity, and the highest specific heat and thermal conductivity of all gases. [citation needed]