Search results
Results from the WOW.Com Content Network
α-Aminobutyric acid (AABA), also known as homoalanine in biochemistry, is a non-proteinogenic alpha amino acid with chemical formula C 4 H 9 NO 2. The straight two carbon side chain is one carbon longer than alanine, hence the prefix homo-. Homoalanine is biosynthesised by transaminating oxobutyrate, a metabolite in isoleucine biosynthesis.
β-Aminobutyric acid (BABA) is an isomer of the amino acid aminobutyric acid with the chemical formula C 4 H 9 NO 2.It has two isomers, α-aminobutyric acid and γ-aminobutyric acid (GABA), a neurotransmitter in animals that is also found in plants, where it may play a role in signalling.
The Strecker amino acid synthesis, also known simply as the Strecker synthesis, is a method for the synthesis of amino acids by the reaction of an aldehyde with cyanide in the presence of ammonia. The condensation reaction yields an α-aminonitrile, which is subsequently hydrolyzed to give the desired amino acid.
Homocystine is the organosulfur compound with the formula (HO 2 CCH(NH 2)CH 2 CH 2 S) 2. It is disulfide derived from oxidation of homocysteine . [ 2 ] Its relationship with homocysteine is analogous to the relationship between cystine and cysteine .
3), and carbon dioxide (CO 2) in order to maintain pH in the blood and duodenum, among other tissues, to support proper metabolic function. [1] Catalyzed by carbonic anhydrase, carbon dioxide (CO 2) reacts with water (H 2 O) to form carbonic acid (H 2 CO 3), which in turn rapidly dissociates to form a bicarbonate ion (HCO −
Allylic shifts become the dominant reaction pathway when there is substantial resistance to a normal (non-allylic) substitution. For nucleophilic substitution, such resistance is known when there is substantial steric hindrance at or around the leaving group, or if there is a geminal substituent destabilizing an accumulation of positive charge.
Formic acid (HCO 2 H) 3.75 Chloroformic acid (ClCO 2 H) 0.27 [5] Acetic acid (CH 3 CO 2 H) 4.76 Glycine (NH 2 CH 2 CO 2 H) 2.34 Fluoroacetic acid (FCH 2 CO 2 H) 2.586 Difluoroacetic acid (F 2 CHCO 2 H) 1.33 Trifluoroacetic acid (CF 3 CO 2 H) 0.23 Chloroacetic acid (ClCH 2 CO 2 H) 2.86 Dichloroacetic acid (Cl 2 CHCO 2 H) 1.29 Trichloroacetic ...
As an example, electrolysis of acetic acid yields ethane and carbon dioxide: CH 3 COOH → CH 3 COO − → CH 3 COO· → CH 3 · + CO 2 2CH 3 · → CH 3 CH 3. Another example is the synthesis of 2,7-dimethyl-2,7-dinitrooctane from 4-methyl-4-nitrovaleric acid: [3] The Kolbe reaction has also been occasionally used in cross-coupling reactions.