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Lyman-alpha, typically denoted by Ly-α, is a spectral line of hydrogen (or, more generally, of any one-electron atom) in the Lyman series. It is emitted when the atomic electron transitions from an n = 2 orbital to the ground state ( n = 1), where n is the principal quantum number .
The version of the Rydberg formula that generated the Lyman series was: [2] = (= +) where n is a natural number greater than or equal to 2 (i.e., n = 2, 3, 4, .... Therefore, the lines seen in the image above are the wavelengths corresponding to n = 2 on the right, to n → ∞ on the left.
In the case of neutral atomic hydrogen, the minimum ionization energy is equal to the Lyman limit, where the photon has enough energy to completely ionize the atom, resulting in a free proton and a free electron. Above this energy (below this wavelength), all wavelengths of light may be absorbed. This forms a continuum in the energy spectrum ...
Lines are named sequentially starting from the longest wavelength/lowest frequency of the series, using Greek letters within each series. For example, the 2 → 1 line is called "Lyman-alpha" (Ly-α), while the 7 → 3 line is called "Paschen-delta" (Pa-δ). Energy level diagram of electrons in hydrogen atom
The equivalent width of a spectral line is a measure of the area of the line on a plot of intensity versus wavelength in relation to underlying continuum level. It is found by forming a rectangle with a height equal to that of continuum emission, and finding the width such that the area of the rectangle is equal to the area in the spectral line.
The Lyman limit is the short-wavelength end of the hydrogen Lyman series, at 91.13 nm (911.3 Å)(13.6 eV). It corresponds to the energy required for an electron in the hydrogen ground state to escape from the electric potential barrier that originally confined it, thus creating a hydrogen ion. [1] This energy is equivalent to the Rydberg constant.
Its frequency is thus the Lyman-alpha hydrogen frequency, increased by a factor of (Z − 1) 2. This formula of f = c / λ = (Lyman-alpha frequency) ⋅ ( Z − 1) 2 is historically known as Moseley's law (having added a factor c to convert wavelength to frequency), and can be used to predict wavelengths of the K α (K-alpha) X-ray spectral ...
This equation is known as the Breit–Rabi formula and is useful for systems with one valence electron in an (= /) level. [ 9 ] [ 10 ] Note that index F {\displaystyle F} in Δ E F = I ± 1 / 2 {\displaystyle \Delta E_{F=I\pm 1/2}} should be considered not as total angular momentum of the atom but as asymptotic total angular momentum .