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Pozzolans are a broad class of siliceous and aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH) 2) at ordinary temperature to form compounds possessing cementitious properties. [1]
Pozzolana from Mount Vesuvius volcano, Italy. Pozzolana or pozzuolana (/ ˌ p ɒ t s (w) ə ˈ l ɑː n ə / POT-s(w)ə-LAH-nə, Italian: [potts(w)oˈlaːna]), also known as pozzolanic ash (Latin: pulvis puteolanus), is a natural siliceous or siliceous-aluminous material which reacts with calcium hydroxide in the presence of water at room temperature (cf. pozzolanic reaction).
The pozzolanic reaction is the chemical reaction that occurs in portland cement upon the addition of pozzolans. It is the main reaction involved in the Roman concrete invented in Ancient Rome and used to build, for example, the Pantheon. The pozzolanic reaction converts a silica-rich precursor with no cementing properties, to a calcium silicate ...
Compared to using Portland cement, the resulting concrete-mix using EMC does not require a higher "total cementitious content" to meet strength-development requirements. In testing by BASF, the 28-day strength-development for 55% replacement of Portland cement by a natural pozzolanic EMC was 14,000 psi / 96.5 MPa (i.e. > C95). This comprised a ...
The setting of pozzolanic cements has much in common with setting of their modern counterpart, Portland cement. The high silica composition of Roman pozzolana cements is very close to that of modern cement to which blast furnace slag , fly ash , or silica fume have been added.
Portland pozzolan cement includes fly ash cement, since fly ash is a pozzolan, but also includes cements made from other natural or artificial pozzolans. In countries where volcanic ashes are available (e.g., Italy, Chile, Mexico, the Philippines), these cements are often the most common form in use.
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All things being equal, concrete with a lower water-cement (cementitious) ratio makes a stronger concrete than that with a higher ratio. [2] The total quantity of cementitious materials (portland cement, slag cement, pozzolans) can affect strength, water demand, shrinkage, abrasion resistance and density. All concrete will crack independent of ...