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The square wave in mathematics has many definitions, which are equivalent except at the discontinuities: It can be defined as simply the sign function of a sinusoid: = () = () = () = (), which will be 1 when the sinusoid is positive, −1 when the sinusoid is negative, and 0 at the discontinuities.
Consequently, the wave function also became a four-component function, governed by the Dirac equation that, in free space, read (+ (= )) =. This has again the form of the Schrödinger equation, with the time derivative of the wave function being given by a Hamiltonian operator acting upon the wave function.
In this case, the wave functions are square integrable. One can initially take the function space as the space of square integrable functions, usually denoted L 2. The displayed functions are solutions to the Schrödinger equation. Obviously, not every function in L 2 satisfies the Schrödinger equation for the hydrogen atom.
A modulated wave resulting from adding two sine waves of identical amplitude and nearly identical wavelength and frequency. A common situation resulting in an envelope function in both space x and time t is the superposition of two waves of almost the same wavelength and frequency: [2]
The Coulomb wave equation for a single charged particle of mass is the Schrödinger equation with Coulomb potential [1] (+) = (),where = is the product of the charges of the particle and of the field source (in units of the elementary charge, = for the hydrogen atom), is the fine-structure constant, and / is the energy of the particle.
The time-independent Schrödinger equation for the wave function is ^ = [+ ()] = (), where Ĥ is the Hamiltonian, ħ is the reduced Planck constant, m is the mass, E the energy of the particle. The step potential is simply the product of V 0 , the height of the barrier, and the Heaviside step function : V ( x ) = { 0 , x < 0 V 0 , x ≥ 0 ...
= if and only if is exactly equal to the wave function of the ground state of the studied system. The variational principle formulated above is the basis of the variational method used in quantum mechanics and quantum chemistry to find approximations to the ground state.
The Born rule is a postulate of quantum mechanics that gives the probability that a measurement of a quantum system will yield a given result. In one commonly used application, it states that the probability density for finding a particle at a given position is proportional to the square of the amplitude of the system's wavefunction at that position.