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This compound causes rainfall pH to be around 5.0–5.5. When rainfall has a lower pH than natural levels, it can cause rapid acidification of soil. Sulfur dioxide and nitrogen oxides are precursors of stronger acids that can lead to acid rain production when they react with water in the atmosphere
Volcanic activity can release sulfur dioxide (SO₂) and other acidic oxides into the atmosphere. [8] In air, sulfur dioxide converts to sulfuric acid: [9] This sulfuric acid dissociates into sulfate ions (SO₄²⁻) and hydrogen ions (H⁺), increasing the acidic condition. SO 2 + ½ O 2 + H 2 O → H 2 SO 4; H 2 SO 4 → 2H⁺ + SO 4 2 ⁻
The amount of sulfur dioxide that can be emitted into the atmosphere is capped by the EPA. This reduces the quantity of sulfur dioxide in the air that turns into sulfur trioxide and sulfuric acid. [14] Sulfuric acid concentrations in workroom air are restricted by OSHA to 1 mg/m 3. Moreover, NIOSH advises a time-weighted average limit of 1 mg/m ...
Title IV of the Clean Air Act Amendments of 1990 established the allowance market system known today as the Acid Rain Program. Initially targeting only sulfur dioxide, Title IV set a decreasing cap on total SO 2 emissions for each of the following several years, aiming to reduce overall emissions to 50% of 1980 levels.
The prevailing view in the 1940s and 1950s was that P availability was maximized near neutrality (soil pH 6.5–7.5), and decreased at higher and lower pH. [ 29 ] [ 30 ] Interactions of phosphorus with pH in the moderately to slightly acidic range (pH 5.5–6.5) are, however, far more complex than is suggested by this view.
Consequently, acid sulfate soil samples should be immediately cooled to < 4°C to slow oxidation; and samples containing monosulfidic material should be immediately frozen (e.g., using a portable freezer or liquid nitrogen). [31] The use of dry ice is recommended as the gaseous carbon dioxide should further hinder oxidation.
Soil gases (soil atmosphere [1]) are the gases found in the air space between soil components. The spaces between the solid soil particles, if they do not contain water, are filled with air. The primary soil gases are nitrogen, carbon dioxide and oxygen. [2] Oxygen is critical because it allows for respiration of both plant roots and soil ...
The microbial decomposers assimilate the monomers (3) and either mineralize these into inorganic compounds like carbon dioxide or ammonium (4) or use the monomers for their biosynthetic needs. N mineralization leads to a loss of ammonium to the environment (5), but this process is only relevant if the organic matter has a low C:N ratio.
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