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The statement of Newton's law used in the heat transfer literature puts into mathematics the idea that the rate of heat loss of a body is proportional to the difference in temperatures between the body and its surroundings. For a temperature-independent heat transfer coefficient, the statement is:
Substituting into the Clapeyron equation =, we can obtain the Clausius–Clapeyron equation [8]: 509 = for low temperatures and pressures, [8]: 509 where is the specific latent heat of the substance. Instead of the specific, corresponding molar values (i.e. L {\displaystyle L} in kJ/mol and R = 8.31 J/(mol⋅K)) may also be used.
The terms sensible heat and latent heat refer to energy transferred between a body and its surroundings, defined by the occurrence or non-occurrence of temperature change; they depend on the properties of the body. Sensible heat is sensed or felt in a process as a change in the body's temperature.
Calorimetry requires that a reference material that changes temperature have known definite thermal constitutive properties. The classical rule, recognized by Clausius and Kelvin, is that the pressure exerted by the calorimetric material is fully and rapidly determined solely by its temperature and volume; this rule is for changes that do not involve phase change, such as melting of ice.
Since heat density is proportional to temperature in a homogeneous medium, the heat equation is still obeyed in the new units. Suppose that a body obeys the heat equation and, in addition, generates its own heat per unit volume (e.g., in watts/litre - W/L) at a rate given by a known function q varying in space and time. [ 5 ]
(Note - the relation between pressure, volume, temperature, and particle number which is commonly called "the equation of state" is just one of many possible equations of state.) If we know all k+2 of the above equations of state, we may reconstitute the fundamental equation and recover all thermodynamic properties of the system.
When the Biot number is greater than 0.1 or so, the heat equation must be solved to determine the time-varying and spatially-nonuniform temperature field within the body. Analytic methods for handling these problems, which may exist for simple geometric shapes and uniform material thermal conductivity , are described in the article on the heat ...
The contemporary conjugate convective heat transfer model was developed after computers came into wide use in order to substitute the empirical relation of proportionality of heat flux to temperature difference with heat transfer coefficient which was the only tool in theoretical heat convection since the times of Newton. This model, based on a ...