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Bis(pinacolato)diboron is a covalent compound containing two boron atoms and two pinacolato ligands. It has the formula [(CH 3) 4 C 2 O 2 B] 2; the pinacol groups are sometimes abbreviated as "pin", so the structure is sometimes represented as B 2 pin 2. It is a colourless solid that is soluble in organic solvents.
Structure of a rare monomeric boron hydride, R = i-Pr. [4] The most-studied class of organoboron compounds has the formula BR n H 3−n. These compounds are catalysts, reagents, and synthetic intermediates. The trialkyl and triaryl derivatives feature a trigonal-planar boron center that is typically only weakly Lewis acidic.
Dibutylboron trifluoromethanesulfonate (also called dibutylboron triflate or DBBT) is a reagent in organic chemistry. Its chemical formula is C 9 H 18 BF 3 O 3 S. It is used in asymmetric synthesis for example in the formation of boron enolates in the aldol reaction. [1]
9-Borabicyclo[3.3.1]nonane or 9-BBN is an organoborane compound. This colourless solid is used in organic chemistry as a hydroboration reagent.The compound exists as a hydride-bridged dimer, which easily cleaves in the presence of reducible substrates.
In the US, a team led by Schlesinger developed the basic chemistry of the anionic boron hydrides and the related aluminium hydrides. Schlesinger's work laid the foundation for a host of boron hydride reagents for organic synthesis, most of which were developed by his student Herbert C. Brown. Borane-based reagents are now widely used in organic ...
The origin of selectivity for aliphatic C–H borylation using rhodium catalysts was probed using a type of mechanistic study called hydrogen–deuterium exchange. H/D exchanged showed that regioselectivity of the overall process shown below results from selective cleavage of primary over secondary C–H bonds and selective functionalization of ...
Diisopinocampheylborane is an organoborane that is useful for asymmetric synthesis. This colourless solid is the precursor to a range of related reagents. The compound was reported in 1961 by Zweifel and Brown in a pioneering demonstration of asymmetric synthesis using boranes. The reagent is mainly used for the synthesis of chiral secondary ...
This chemical reaction is useful in the organic synthesis of organic compounds. [1] Hydroboration produces organoborane compounds that react with a variety of reagents to produce useful compounds, such as alcohols, amines, or alkyl halides. The most widely known reaction of the organoboranes is oxidation to produce alcohols from alkenes.