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Nitrogen-15 is frequently used in NMR (Nitrogen-15 NMR spectroscopy). Unlike the more abundant nitrogen-14, which has an integer nuclear spin and thus a quadrupole moment, 15 N has a fractional nuclear spin of one-half, which offers advantages for NMR such as narrower line width. Nitrogen-15 tracing is a technique used to study the nitrogen cycle.
Examples include carbon-14, nitrogen-15, and oxygen-16 in the table above. Isobars are nuclides with the same number of nucleons (i.e. mass number) but different numbers of protons and neutrons. Isobars neighbor each other diagonally from lower-left to upper-right. Examples include carbon-14, nitrogen-14, and oxygen-14 in the table above.
Nitrogen-15 (15 N) tracing is a technique to study the nitrogen cycle using the heavier, stable nitrogen isotope 15 N.Despite the different weights, 15 N is involved in the same chemical reactions as the more abundant 14 N and is therefore used to trace and quantify conversions of one nitrogen compound to another.
Oxygen-15 is a radioisotope, often used in positron emission tomography (PET). It can be used in, among other things, water for PET myocardial perfusion imaging and for brain imaging. [20] [21] It has an atomic mass of 15.003 0656 (5), and a half-life of 122.266(43) s. It is produced through deuteron bombardment of nitrogen-14 using a cyclotron ...
An example of cosmic ray spallation is a neutron hitting a nitrogen-14 nucleus in the Earth's atmosphere, yielding a proton, an alpha particle, and a beryllium-10 nucleus, which eventually decays to boron-10. Alternatively, a proton can hit oxygen-16, yielding two protons, a neutron, and again an alpha particle and a beryllium-10 nucleus.
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15 N NMR is the most effective method for investigation of structure of heterocycles with a high content of nitrogen atoms (tetrazoles, triazines and their annelated analogs). [7] [8] 15 N labeling followed by analysis of 13 C– 15 N and 1 H– 15 N couplings may be used for establishing structures and chemical transformations of nitrogen ...
The difference is whether the relative abundance is with respect to all the nitrogen, i.e. 14 N plus 15 N, or just to 14 N. Since the atmosphere is 99.6337% 14 N and 0.3663% 15 N, a is 0.003663 in the former case and 0.003663/0.996337 = 0.003676 in the latter.
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