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This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The resulting ternary azeotrope is neither positive nor negative. Its boiling point falls between the boiling points of acetone and chloroform, so it is neither a maximum nor a minimum boiling point. This type of system is called a saddle azeotrope. [13] Only systems of three or more constituents can form saddle azeotropes.
8 Boiling points of aqueous solutions. 9 Charts. 10 References. Toggle the table of contents. Ethanol (data page) ... (including azeotrope)
Normal boiling points for pure substances, bubble and dew points for zeotropic blends, or normal boiling point and azeotropic temperature for the azeotropic blends, at 101,325 Pa (1 atmosphere) and in degrees Celsius; Critical temperature in degrees Celsius; Absolute critical pressure in kilopascals
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; ... Toggle the table of contents. List of boiling and freezing information ...
An azeotrope is not a range of concentrations that cannot be distilled, but the point at which the activity coefficients of the distillates are crossing one another. If the azeotrope can be "jumped over", distillation can continue, although because the activity coefficients have crossed, the component which is boiling will change.
At standard pressure, the mixture of water and dioxane in the ratio 17.9:82.1 by mass is a positive azeotrope that boils at 87.6 °C. [16] The oxygen atoms are weakly Lewis-basic. It forms adducts with a variety of Lewis acids. It is classified as a hard base and its base parameters in the ECW model are E B = 1.86 and C B = 1.29.
Stability of residue curves in the vicinity of binary azeotropes. Pure components and azeotropic points are called nodes. Three different types are possible: Stable node: This is the pure component or the azeotropic point with the highest boiling temperature and lowest vapor pressure in a distillation region. All residue curves end at stable nodes.