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Methane clathrate block embedded in the sediment of hydrate ridge, off Oregon, USA. Clathrate hydrates, or gas hydrates, clathrates, or hydrates, are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules.
In 1935, Linus Pauling used the ice rules to calculate the residual entropy (zero temperature entropy) of ice I h. [3] For this (and other) reasons the rules are sometimes mis-attributed and referred to as "Pauling's ice rules" (not to be confused with Pauling's rules for ionic crystals). A nice figure of the resulting structure can be found in ...
Fast ice (also called land-fast ice, landfast ice, and shore-fast ice) is sea ice or lake ice [1] that is "fastened" to the coastline, to the sea floor along shoals, or to grounded icebergs. [ 2 ] [ 3 ] [ 4 ] Fast ice may either grow in place from the sea water or by freezing pieces of drifting ice to the shore or other anchor sites.
When water freezes, most impurities are excluded from the water crystals; even ice from seawater is relatively fresh compared to the seawater from which it is formed. As a result of forcing the impurities out (such as salt and other ions) sea ice is very porous and spongelike, quite different from the solid ice produced when fresh water freezes.
Water molecules in ice I h are surrounded by four semi-randomly directed hydrogen bonds. Such arrangements should change to the more ordered arrangement of hydrogen bonds found in ice XI at low temperatures, so long as localized proton hopping is sufficiently enabled; a process that becomes easier with increasing pressure. [104]
The O−O bond length is within 2 pm of the 120.7 pm distance for the O=O double bond in the dioxygen molecule, O 2 . Several bonding systems have been proposed to explain this, including an O−O triple bond with O−F single bonds destabilised and lengthened by repulsion between the lone pairs on the fluorine atoms and the π orbitals of the ...
Unlike polynyas, which tend to occur, and remain, at a given location, leads are transient features that can form anywhere in an ice-covered ocean. [6] Moreover, while the origin of polynyas is linked with either warm air current circulation from the coastline or a warm water upwelling, the driving force behind lead formation is a state of stress, either wind- or current-induced, within the ...
The bond energy is significantly weaker than those of Cl 2 or Br 2 molecules and similar to the easily cleaved oxygen–oxygen bonds of peroxides or nitrogen–nitrogen bonds of hydrazines. [8] The covalent radius of fluorine of about 71 picometers found in F 2 molecules is significantly larger than that in other compounds because of this weak ...