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For a typical second-order reaction with rate equation = [] [], if the concentration of reactant B is constant then = [] [] = ′ [], where the pseudo–first-order rate constant ′ = []. The second-order rate equation has been reduced to a pseudo–first-order rate equation, which makes the treatment to obtain an integrated rate equation much ...
[A] can provide intuitive insight about the order of each of the reagents. If plots of v / [A] vs. [B] overlay for multiple experiments with different-excess, the data are consistent with a first-order dependence on [A]. The same could be said for a plot of v / [B] vs. [A]; overlay is consistent with a first-order dependence on [B].
Pages for logged out editors learn more. Contributions; Talk; Pseudo first order reaction
Although these equations were derived to assist with predicting the time course of drug action, [1] the same equation can be used for any substance or quantity that is being produced at a measurable rate and degraded with first-order kinetics. Because the equation applies in many instances of mass balance, it has very broad applicability in ...
In chemical kinetics, the pre-exponential factor or A factor is the pre-exponential constant in the Arrhenius equation (equation shown below), an empirical relationship between temperature and rate coefficient. It is usually designated by A when determined from experiment, while Z is usually left for collision frequency. The pre-exponential ...
The advantage of using low-discrepancy sequences is a faster rate of convergence. Quasi-Monte Carlo has a rate of convergence close to O(1/N), whereas the rate for the Monte Carlo method is O(N −0.5). [1] The Quasi-Monte Carlo method recently became popular in the area of mathematical finance or computational finance. [1]
For the second-order approximations of the third central moment as well as for the derivation of all higher-order approximations see Appendix D of Ref. [3] Taking into account the quadratic terms of the Taylor series and the third moments of the input variables is referred to as second-order third-moment method. [4]
Blum Blum Shub takes the form + =, where M = pq is the product of two large primes p and q.At each step of the algorithm, some output is derived from x n+1; the output is commonly either the bit parity of x n+1 or one or more of the least significant bits of x n+1.