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Clemmensen reduction is a chemical reaction described as a reduction of ketones or aldehydes to alkanes using zinc amalgam and concentrated hydrochloric acid (HCl). [1] [2] This reaction is named after Erik Christian Clemmensen, a Danish-American chemist. [3] Scheme 1: Reaction scheme of Clemmensen Reduction.
Lucas test: negative (left) with ethanol and positive with t-butanol "Lucas' reagent" is a solution of anhydrous zinc chloride in concentrated hydrochloric acid.This solution is used to classify alcohols of low molecular weight.
Zincates are anionic zinc complexes. Related to the preparation of Lucas' reagent, tetrachlorozincates are often generated by combining hydrochloric acid and zinc chloride. A related anion is [Zn 2 Cl 6] 2−, in which again Zn(II) adopts a tetrahedral geometry. [2]
Zinc chloride is an inorganic chemical compound with the formula ZnCl 2 ·nH 2 O, with n ranging from 0 to 4.5, forming hydrates.Zinc chloride, anhydrous and its hydrates, are colorless or white crystalline solids, and are highly soluble in water.
Acid is needed to protonate the resulting alkoxide during work up. The initial step is an oxidative addition of zinc metal into the carbon-halogen bond, thus forming a carbon-zinc enolate. This C-Zn enolate can then rearrange to the Oxygen-Zinc enolate via coordination.
Zinc chloride smoke is grey-white and consists of tiny particles of zinc chloride. The most common mixture for generating these is a zinc chloride smoke mixture (HC), consisting of hexachloroethane, grained aluminium and zinc oxide. The smoke consists of zinc chloride, zinc oxychlorides, and hydrochloric acid, which absorb the moisture in
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It is assumed that the reported solubility of zinc aspartate in diluted hydrochloric acid will allow its dissociation and absorption in the stomach. However, it was not clear if further absorption could take place in the intestine considering its reported insolubility in water. [2]