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As ammonium nitrate is a salt, both the cation, NH + 4, and the anion, NO − 3, may take part in chemical reactions. Solid ammonium nitrate decomposes on heating. At temperatures below around 300 °C, the decomposition mainly produces nitrous oxide and water: NH 4 NO 3 → N 2 O + 2 H 2 O. At higher temperatures, the following reaction ...
For example, energy is released by the oxidation of ammonium in a process known as nitrification, which produces nitrate and nitrite. [6] This process is a form of autotrophy that is common amongst Nitrosomonas , Nitrobacter , Nitrosolobus , and Nitrosospira , amongst others.
The process of nitrification begins with the first stage of ammonia oxidation, where ammonia (NH 3) or ammonium (NH 4 +) get converted into nitrite (NO 2-). This first stage is sometimes known as nitritation. It is performed by two groups of organisms, ammonia-oxidizing bacteria (AOB) and ammonia-oxidizing archaea (AOA [2]).
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero.
The oxidation states are also maintained in articles of the elements (of course), and systematically in the table {{Infobox element/symbol-to-oxidation-state}}
In the primary stage of nitrification, the oxidation of ammonium (NH + 4) is performed by bacteria such as the Nitrosomonas species, which converts ammonia to nitrites (NO − 2). Other bacterial species such as Nitrobacter , are responsible for the oxidation of the nitrites ( NO − 2 ) into nitrates ( NO − 3 ).
[12] [13] Complete nitrification, the conversion of ammonia to nitrate in a single step known as comammox, has an energy yield (∆G°′) of −349 kJ mol −1 NH 3, while the energy yields for the ammonia-oxidation and nitrite-oxidation steps of the observed two-step reaction are −275 kJ mol −1 NH 3, and −74 kJ mol −1 NO 2 − ...
Ammonium dichromate is an inorganic compound with the formula (NH 4) 2 Cr 2 O 7.In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium.