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The classic example of a dehydration reaction is the Fischer esterification, which involves treating a carboxylic acid with an alcohol to give an ester RCO 2 H + R′OH ⇌ RCO 2 R′ + H 2 O Often such reactions require the presence of a dehydrating agent, i.e. a substance that reacts with water.
Condensation reactions likely played major roles in the synthesis of the first biotic molecules including early peptides and nucleic acids.In fact, condensation reactions would be required at multiple steps in RNA oligomerization: the condensation of nucleobases and sugars, nucleoside phosphorylation, and nucleotide polymerization.
The Robinson–Gabriel synthesis is an organic reaction in which a 2-acylamino-ketone reacts intramolecularly followed by a dehydration to give an oxazole.A cyclodehydrating agent is needed to catalyze the reaction [1] [2] [3] It is named after Sir Robert Robinson and Siegmund Gabriel who described the reaction in 1909 and 1910, respectively.
Another useful example is the one pot two-step synthesis of halfordinol, a parent compound for Rutaceae alkaloids. The initial steps follow the Fischer oxazole synthesis, although the acid-catalyzed cyclization occurs in two steps rather than one, which ensures the formation of the di-chloro intermediate, preventing formation of the regioisomer ...
Gully – Landform created by running water and/or mass movement eroding sharply into soil; Hill – Landform that extends above the surrounding terrain; Hillock, also known as Knoll – Small hill; Mesa – Elevated area of land with a flat top and sides, usually much wider than buttes; Mountain pass – Route through a mountain range or over ...
The conditions of these vents have been shown to support the synthesis of molecules important to life. Some evidence suggests that certain vents such as alkaline hydrothermal vents or those containing supercritical CO 2 are more conducive to the formation of these organic molecules. However, the origin of life is a widely debated topic, and ...
Lilly Jay is reflecting on the fallout after her marriage with Ethan Slater ended.. In an essay for The Cut published Thursday, Dec. 18, Jay, a clinical psychologist specializing in perinatal ...
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