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  2. Epimer - Wikipedia

    en.wikipedia.org/wiki/Epimer

    In stereochemistry, an epimer is one of a pair of diastereomers. [1] The two epimers have opposite configuration at only one stereogenic center out of at least two. [2] All other stereogenic centers in the molecules are the same in each. Epimerization is the interconversion of one epimer to the other epimer.

  3. Stereochemistry - Wikipedia

    en.wikipedia.org/wiki/Stereochemistry

    Stereochemistry, a subdiscipline of chemistry, studies the spatial arrangement of atoms that form the structure of molecules and their manipulation. [1] The study of stereochemistry focuses on the relationships between stereoisomers, which are defined as having the same molecular formula and sequence of bonded atoms (constitution) but differing in the geometric positioning of the atoms in space.

  4. Stereoisomerism - Wikipedia

    en.wikipedia.org/wiki/Stereoisomerism

    The proper name for this molecule is either trans-2-fluoro-3-methylpent-2-ene because the alkyl groups that form the backbone chain (i.e., methyl and ethyl) reside across the double bond from each other, or (Z)-2-fluoro-3-methylpent-2-ene because the highest-priority groups on each side of the double bond are on the same side of the double bond ...

  5. Cis–trans isomerism - Wikipedia

    en.wikipedia.org/wiki/Cis–trans_isomerism

    Very often, cis–trans stereoisomers contain double bonds or ring structures. In both cases the rotation of bonds is restricted or prevented. [4] When the substituent groups are oriented in the same direction, the diastereomer is referred to as cis, whereas when the substituents are oriented in opposing directions, the diastereomer is referred to as trans.

  6. Diastereomer - Wikipedia

    en.wikipedia.org/wiki/Diastereomer

    When the single bond between the two centres is free to rotate, cis/trans descriptors become invalid. Two widely accepted prefixes used to distinguish diastereomers on sp³-hybridised bonds in an open-chain molecule are syn and anti. Masamune proposed the descriptors which work even if the groups are not attached to adjacent carbon atoms.

  7. Woman accused of stowing away on flight from NY to Paris ...

    www.aol.com/news/woman-accused-stowing-away...

    Svetlana Dali, the woman accused of stowing away on a flight from New York to Paris, was arrested again, according to the FBI.

  8. Stereocenter - Wikipedia

    en.wikipedia.org/wiki/Stereocenter

    Two enantiomers of a generic amino acid at the stereocenter. In stereochemistry, a stereocenter of a molecule is an atom (center), axis or plane that is the focus of stereoisomerism; that is, when having at least three different groups bound to the stereocenter, interchanging any two different groups creates a new stereoisomer.

  9. Katie Holmes Recalls What Happened When She Forgot Her Lines ...

    www.aol.com/katie-holmes-recalls-happened-she...

    Katie Holmes understands the show must go on. The actress stopped by The Tonight Show Starring Jimmy Fallon Nov. 27 to discuss her role playing Mrs. Webb in the Broadway revival of Our Town ...