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Both the negatively charged anion HO −, called hydroxide, and the neutral radical HO·, known as the hydroxyl radical, consist of an unbonded hydroxy group. According to IUPAC definitions, the term hydroxyl refers to the hydroxyl radical (·OH) only, while the functional group −OH is called a hydroxy group. [1]
Hydroxide is a diatomic anion with chemical formula OH −. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst.
The solvent used can also assist in the stabilization of the negative charge on a conjugated base. Bases used to deprotonate depend on the p K a of the compound. When the compound is not particularly acidic , and, as such, the molecule does not give up its proton easily, a base stronger than the commonly known hydroxides is required.
Skeletal formulae of 1-hydroxy-2()-pyridinethione and its tautomer. The hydroxyl radical, • HO, is the neutral form of the hydroxide ion (HO –).Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of radical chemistry.
The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons [2] (e.g. K + (potassium ion)) while an anion is a negatively charged ion with more electrons than protons. [3] (e.g. Cl-(chloride ion) and OH-(hydroxide
The charge of the resulting ions is a major factor in the strength of ionic bonding, e.g. a salt C + A − is held together by electrostatic forces roughly four times weaker than C 2+ A 2− according to Coulomb's law, where C and A represent a generic cation and anion respectively. The sizes of the ions and the particular packing of the ...
In an ionization reaction, as in all reactions that involve leaving group departure, the leaving group bears a larger negative charge in the transition state and products than it does in the starting materials. The correlation between pK aH and leaving group ability, however, is not perfect.
The positively charged sodium ions Na + will react toward the cathode, neutralizing the negative charge of OH − there, and the negatively charged hydroxide ions OH − will react toward the anode, neutralizing the positive charge of Na + there.