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The process of absorption means that a substance captures and transforms energy. The absorbent distributes the material it captures throughout whole and adsorbent only distributes it through the surface. The process of gas or liquid which penetrate into the body of adsorbent is commonly known as absorption.
VSA typically draws the gas through the separation process with a vacuum. For oxygen and nitrogen VSA systems, the vacuum is typically generated by a blower. Hybrid vacuum pressure swing adsorption (VPSA) systems also exist. VPSA systems apply pressurized gas to the separation process and also apply a vacuum to the purge gas.
Adsorption is the adhesion [1] of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. [2] This process creates a film of the adsorbate on the surface of the adsorbent. This process differs from absorption, in which a fluid (the absorbate) is dissolved by or permeates a liquid or solid (the absorbent). [3]
where is the fractional occupancy of the adsorption sites, i.e., the ratio of the volume V of gas adsorbed onto the solid to the volume of a gas molecules monolayer covering the whole surface of the solid and completely occupied by the adsorbate. A continuous monolayer of adsorbate molecules covering a homogeneous flat solid surface is the ...
BET model of multilayer adsorption, that is, a random distribution of sites covered by one, two, three, etc., adsorbate molecules. The concept of the theory is an extension of the Langmuir theory, which is a theory for monolayer molecular adsorption, to multilayer adsorption with the following hypotheses:
Gas–liquid absorption (a) and liquid–solid adsorption (b) mechanism. Blue spheres are solute molecules. Sorption is a physical and chemical process by which one substance becomes attached to another. Specific cases of sorption are treated in the following articles: Absorption
Liquefaction of gases is physical conversion of a gas into a liquid state (condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders.
This process requires constant temperature, close to ambient. With this process, nitrogen is produced by the plant at the above-atmospheric pressure, while the adsorbent regeneration is accomplished at below-atmospheric pressure. The swing adsorption process in each of the two adsorbers consists of two stages running for a few minutes.