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  2. Elementary reaction - Wikipedia

    en.wikipedia.org/wiki/Elementary_reaction

    An elementary reaction is a chemical reaction in which one or more chemical species react directly to form products in a single reaction step and with a single transition state. In practice, a reaction is assumed to be elementary if no reaction intermediates have been detected or need to be postulated to describe the reaction on a molecular ...

  3. Chemical reaction - Wikipedia

    en.wikipedia.org/wiki/Chemical_reaction

    The elementary reaction is the smallest division into which a chemical reaction can be decomposed, it has no intermediate products. [13] Most experimentally observed reactions are built up from many elementary reactions that occur in parallel or sequentially. The actual sequence of the individual elementary reactions is known as reaction ...

  4. Reaction step - Wikipedia

    en.wikipedia.org/wiki/Reaction_step

    In chemistry, a reaction step of a chemical reaction is defined as: "An elementary reaction, constituting one of the stages of a stepwise reaction in which a reaction intermediate (or, for the first step, the reactants) is converted into the next reaction intermediate (or, for the last step, the products) in the sequence of intermediates between reactants and products". [1]

  5. Reaction mechanism - Wikipedia

    en.wikipedia.org/wiki/Reaction_mechanism

    In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. [1] A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases.

  6. Rate equation - Wikipedia

    en.wikipedia.org/wiki/Rate_equation

    If the reaction goes to completion, the rate equation for the reaction rate = [] [] applies throughout the course of the reaction. Elementary (single-step) reactions and reaction steps have reaction orders equal to the stoichiometric coefficients for each reactant.

  7. Molecularity - Wikipedia

    en.wikipedia.org/wiki/Molecularity

    The order of reaction is an empirical quantity determined by experiment from the rate law of the reaction. It is the sum of the exponents in the rate law equation. [10] Molecularity, on the other hand, is deduced from the mechanism of an elementary reaction, and is used only in context of an elementary reaction.

  8. Dying To Be Free - The Huffington Post

    projects.huffingtonpost.com/dying-to-be-free...

    The last image we have of Patrick Cagey is of his first moments as a free man. He has just walked out of a 30-day drug treatment center in Georgetown, Kentucky, dressed in gym clothes and carrying a Nike duffel bag.

  9. Law of mass action - Wikipedia

    en.wikipedia.org/wiki/Law_of_mass_action

    However, all reactions can be represented as a series of elementary reactions and, if the mechanism is known in detail, the rate equation for each individual step is given by the expression so that the overall rate equation can be derived from the individual steps. When this is done the equilibrium constant is obtained correctly from the rate ...