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Electroosmotic flow is caused by the Coulomb force induced by an electric field on net mobile electric charge in a solution. Because the chemical equilibrium between a solid surface and an electrolyte solution typically leads to the interface acquiring a net fixed electrical charge, a layer of mobile ions, known as an electrical double layer or Debye layer, forms in the region near the interface.
Electroosmosis is the motion of liquid induced by an applied potential across a porous material, capillary tube, membrane or any other fluid conduit. Electroosmotic flow is caused by the Coulomb force induced by an electric field on net mobile electric charge in a solution.
Capillary electrophoresis is a separation technique which uses high electric field to produce electroosmotic flow for separation of ions. Analytes migrate from one end of capillary to other based on their charge, viscosity and size. Higher the electric field, greater is the mobility.
This is electrocapillary flow, an example of electrocapillarity. Electrocapillary phenomena are phenomena related to changes in the surface free energy (or interfacial tension ) of charged fluid interfaces, for example that of the dropping mercury electrode (DME), or in principle, any electrode, as the electrode potential changes or the ...
Numerous other strategies for covalent modification of capillary surfaces exist. Dynamic or adsorbed coatings (which can include polymers or small molecules) are also common. [9] For example, in capillary sequencing of DNA, the sieving polymer (typically polydimethylacrylamide) suppresses electroosmotic flow to very low levels. [10]
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Electroosmotic flow Electroosmotic flow (or Electro-osmotic flow, often abbreviated EOF) is the motion of liquid induced by an applied potential across a capillary tube or microchannel. Electroosmotic flow is an essential component in chemical separation techniques, notably capillary electrophoresis. Electroosmotic pump