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  2. Nitroethane - Wikipedia

    en.wikipedia.org/wiki/Nitroethane

    Nitroethane is produced industrially by treating propane with nitric acid at 350–450 °C. This exothermic reaction produces four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction involves free radicals, such as CH 3 CH 2 CH 2 O., which arise via homolysis of the corresponding ...

  3. Wacker process - Wikipedia

    en.wikipedia.org/wiki/Wacker_process

    Catalytic cycle for the Wacker process. [8] The initial stoichiometric reaction was first reported by Francis Clifford Phillips in his doctoral dissertation on the composition of Pennsylvanian natural gas defended in 1893. [9] This net reaction can also be described as follows: [PdCl 4] 2 − + C 2 H 4 + H 2 O → CH 3 CHO + Pd + 2 HCl + 2 Cl −

  4. Nitroethylene - Wikipedia

    en.wikipedia.org/wiki/Nitroethylene

    The reaction utilizes benzene as a solvent and proceeds to about 90% yield in 12 hours. [9] Reaction of nitroethylene and aniline. Another example of nitroethylene is from the coupling reaction with a vinyl Grignard reagent and a silyl glyoxalate to form a nitrocylopentanol. This process via a Henry reaction and is highly diastereoselective. [10]

  5. Thermochemical cycle - Wikipedia

    en.wikipedia.org/wiki/Thermochemical_cycle

    Consequently, a thermochemical cycle with i steps can be defined as sequence of i reactions equivalent to water-splitting and satisfying equations (4), (5) and (10). The key point to remember in that case is that the process temperature T H can theoretically be arbitrary chosen (1000K as a reference in most of the past studies, for high ...

  6. Reaction mechanism - Wikipedia

    en.wikipedia.org/wiki/Reaction_mechanism

    In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. [ 1 ] A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction.

  7. Nef reaction - Wikipedia

    en.wikipedia.org/wiki/Nef_reaction

    The reaction has been the subject of several literature reviews. [1] [2] [3] The Nef reaction: 1. Salt of a nitroalkane 3. Ketone 4. Nitrous oxide. The reaction was reported in 1894 by the chemist John Ulric Nef, [4] who treated the sodium salt of nitroethane with sulfuric acid resulting in an 85–89% yield of nitrous oxide and at least 70% ...

  8. 24 Discontinued '70s and '80s Foods That We'll Never ... - AOL

    www.aol.com/finance/24-discontinued-70s-80s...

    3. Keebler Fudge Magic Middles. Neither the chocolate fudge cream inside a shortbread cookie nor versions with peanut butter or chocolate chip crusts survived.

  9. Marine biogeochemical cycles - Wikipedia

    en.wikipedia.org/wiki/Marine_biogeochemical_cycles

    Water is the medium of the oceans, the medium which carries all the substances and elements involved in the marine biogeochemical cycles. Water as found in nature almost always includes dissolved substances, so water has been described as the "universal solvent" for its ability to dissolve so many substances.