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Prior to bringing regulations in line with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) in 2012, OSHA considered flammable liquids to be those with a flash point below 37.8 °C/100 °F. Those with flash points above 37.8 °C/100 °F and below 93.3 °C/200 °F were classified as combustible liquids.
Engines, internal combustion, flammable gas powered or Engines, internal combustion, flammable liquid powered or Vehicle, flammable gas powered or Vehicle, flammable liquid powered UN 3167: 2.1: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid UN 3168: 2.3
Class 3: Flammable Liquids A flammable liquid is a liquid having a flash point of not more than 60 °C (140 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging. The following exceptions ...
Substances and mixtures which, in contact with water, emit flammable gases are categorized from 1 to 3 based on the ignitability of the gas emitted. Oxidizing liquids contribute to the combustion of other materials and are categorized from 1 to 3 in decreasing oxidizing potential. Oxidizing solids follow the same criteria as oxidizing liquids.
Globally Harmonized System of Classification and Labelling of Chemicals uses a four category system to classify flammable liquids using flash point and boiling point temperature. [ 7 ] [ 8 ] This system is used internationally to evaluate and sort substances in industrial applications, workplaces and products distributed to consumers.
Extremely flammable gas H221: Flammable gas H222: Extremely flammable material H223: Flammable material H224: Extremely flammable liquid and vapour H225: Highly flammable liquid and vapour H226: Flammable liquid and vapour H227: Combustible liquid H228: Flammable solid H229: Pressurized container: may burst if heated H230
n.o.s. = not otherwise specified meaning a collective entry to which substances, mixtures, solutions or articles may be assigned if a) they are not mentioned by name in 3.2 Dangerous Goods List AND b) they exhibit chemical, physical and/or dangerous properties corresponding to the Class, classification code, packing group and the name and description of the n.o.s. entry [4]
A liquid material is classed as a Division 5.1 material if, when tested in accordance with the UN Manual of Tests and Criteria, it spontaneously ignites or its mean time for a pressure rise from 690 kPa to 2070 kPa gauge is less than the time of a 1:1 nitric acid (65 percent)/cellulose mixture.
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