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For example, [Ti(H 2 O) 6] 4+ is unknown: the hydrolyzed species [Ti(OH) 2 (H 2 O) n] 2+ is the principal species in dilute solutions. [11] With the higher oxidation states the effective electrical charge on the cation is further reduced by the formation of oxo-complexes.
Calcium hydroxide is moderately soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:
Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
For P CO 2 = 10 −12 atm, the [Ca 2+][OH −] 2 product is still below the solubility product of Ca(OH) 2 (8 × 10 −6). For still lower CO 2 pressure, Ca(OH) 2 precipitation will occur before CaCO 3 precipitation. As ambient CO 2 partial pressure increases to levels above atmospheric, pH drops, and much of the carbonate ion is converted to ...
A volume of 600 m 3 (160,000 US gal) of seawater gives about 1 tonne (2,200 lb) of Mg(OH) 2. Ca(OH) 2 (K sp = 5.02 × 10 −6) [6] is far more soluble than Mg(OH) 2 (K sp = 5.61 × 10 −12) and drastically increases the pH value of seawater from 8.2 to 12.5. The less soluble Mg(OH) 2 precipitates because of the common ion effect due to the OH ...
CO 2 + Ca(OH) 2 → CaCO 3 + H 2 O + heat (in the presence of water) Each mole of CO 2 (44 g) reacts with one mole of calcium hydroxide (74 g) and produces one mole of water (18 g). The reaction can be considered as a strong-base-catalysed, water-facilitated reaction.
Ca(OH) 2 or CaO · H 2 O: Calcium hydroxide (portlandite) C-S-H: 0.6–2.0 CaO · SiO 2 · 0.9–2.5 H 2 O, with variable composition within this range, and often also incorporating partial substitution of Al for Si: Calcium silicate hydrate: C-A-H: Phase more complex than C-S-H: Calcium aluminate hydrate C-A-S-H: This is even more complex than ...
Pentacalcium trialuminate, 5CaO·3Al 2 O 3 (C 5 A 3), forms only under an anhydrous and oxygen free atmosphere. The crystal is orthorhombic, with a density of 3067 kg·m −3. It reacts rapidly with water. Tetracalcium trialuminate, 4CaO·3Al 2 O 3 (C 4 A 3), is a metastable phase formed by dehydrating 4CaO·3Al 2 O 3 ·3H 2 O (C 4 A 3 H 3).