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An oxide (/ ˈ ɒ k s aɪ d /) is a chemical compound containing at least one oxygen atom and one other element [1] in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of –2) of oxygen, an O 2– ion with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials ...
An oxyanion, or oxoanion, is an ion with the generic formula A x O z− y (where A represents a chemical element and O represents an oxygen atom). Oxyanions are formed by a large majority of the chemical elements. [1] The formulae of simple oxyanions are determined by the octet rule. The corresponding oxyacid of an oxyanion is the compound H z ...
A sesquioxide is an oxide of an element (or radical), where the ratio between the number of atoms of that element and the number of atoms of oxygen is 2:3. For example, aluminium oxide Al 2 O 3 and phosphorus(III) oxide P 4 O 6 are sesquioxides.
Compounds containing oxygen in other oxidation states are very uncommon: − 1 ⁄ 2 (superoxides), − 1 ⁄ 3 , 0 (elemental, hypofluorous acid), + 1 ⁄ 2 , +1 (dioxygen difluoride), and +2 (oxygen difluoride). Oxygen is reactive and will form oxides with all other elements except the noble gases helium, neon, argon and krypton. [1]
The −1 occurs because each carbon is bonded to one hydrogen atom (a less electronegative element), and the − 1 / 5 because the total ionic charge of −1 is divided among five equivalent carbons. Again this can be described as a resonance hybrid of five equivalent structures, each having four carbons with oxidation state −1 and ...
Osmium dioxide is another known oxide of osmium, which can be obtained by the reaction of osmium with a variety of oxidizing agents, including, sodium chlorate, osmium tetroxide, and nitric oxide at about 600 °C. [18] [19] It does not dissolve in water, but is attacked by dilute hydrochloric acid. [20] [21] The crystals have rutile structure. [22]
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N.B. Pilling and R.E. Bedworth [2] suggested in 1923 that metals can be classed into two categories: those that form protective oxides, and those that cannot. They ascribed the protectiveness of the oxide to the volume the oxide takes in comparison to the volume of the metal used to produce this oxide in a corrosion process in dry air.