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Graphene is the only form of carbon (or solid material) in which every atom is available for chemical reaction from two sides (due to the 2D structure). Atoms at the edges of a graphene sheet have special chemical reactivity. Graphene has the highest ratio of edge atoms of any allotrope. Defects within a sheet increase its chemical reactivity ...
Graphene is the only form of carbon (or solid material) in which every atom is available for chemical reaction from two sides (due to the 2D structure). Atoms at the edges of a graphene sheet have special chemical reactivity. Graphene has the highest ratio of edge atoms of any allotrope. Defects within a sheet increase its chemical reactivity. [1]
The electronic properties of graphene are significantly influenced by the supporting substrate. [59] [60] The Si(100)/H surface does not perturb graphene's electronic properties, whereas the interaction between it and the clean Si(100) surface changes its electronic states significantly. This effect results from the covalent bonding between C ...
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Bilayer graphene displays the anomalous quantum Hall effect, a tunable band gap [3] and potential for excitonic condensation. [4] Bilayer graphene typically can be found either in twisted configurations where the two layers are rotated relative to each other or graphitic Bernal stacked configurations where half the atoms in one layer lie atop half the atoms in the other. [5]
A typical example of a nanosheet is graphene, the thinnest two-dimensional material (0.34 nm) in the world. [4] It consists of a single layer of carbon atoms with hexagonal lattices . Examples and applications
Graphene has very promising electrical properties. [1] Carbon nanotubes are semimetals meaning they are either metallic or semiconducting along the helical axis, this can depend on the curvature of the graphene helix. On top of having both of these properties graphene has a unique and useful is that it is a "zero-overlap semimetal". [2]
It was studied in detail by Kohlschütter and Haenni in 1918, who described the properties of graphite oxide paper. [9] Its structure was determined from single-crystal diffraction in 1924. [10] The theory of graphene was first explored by P. R. Wallace in 1947 as a starting point for understanding the electronic properties of 3D graphite.