Search results
Results from the WOW.Com Content Network
The mesomeric effect as a result of p-orbital overlap (resonance) has absolutely no effect on this inductive effect, as the inductive effect has purely to do with the electronegativity of the atoms and their topology in the molecule (which atoms are connected to which). Specifically the inductive effect is the tendency for the substituents to ...
The Mössbauer effect, or recoilless nuclear resonance fluorescence, is a physical phenomenon discovered by Rudolf Mössbauer in 1958. It involves the resonant and recoil-free emission and absorption of gamma radiation by atomic nuclei bound in a solid. Its main application is in Mössbauer spectroscopy.
It also termed an effect, oscillations, cycles, or resonance. This effect causes the orbit's argument of pericenter to oscillate about a constant value, which in turn leads to a periodic exchange between its eccentricity and inclination. The process occurs on timescales much longer than the orbital periods.
The pEDA parameter (pi electron donor-acceptor) is a pi-electron substituent effect scale, described also as mesomeric or resonance effect. There is also a complementary scale - sEDA. The more positive is the value of pEDA the more pi-electron donating is a substituent.
In general, the resonance effect of elements in the third period and beyond is relatively weak. This is mainly because of the relatively poor orbital overlap of the substituent's 3p (or higher) orbital with the 2p orbital of the carbon. Due to a stronger resonance effect and inductive effect than the heavier halogens, fluorine is anomalous.
Helmholtz resonance, also known as wind throb, refers to the phenomenon of air resonance in a cavity, an effect named after the German physicist Hermann von Helmholtz. [1] This type of resonance occurs when air is forced in and out of a cavity (the resonance chamber ), causing the air inside to vibrate at a specific natural frequency .
The Mössbauer effect is the resonant and recoil-free emission and absorption of gamma ray photons by atoms bound in a solid form. Resonance in particle physics appears in similar circumstances to classical physics at the level of quantum mechanics and quantum field theory .
The multipactor effect is a phenomenon in radio-frequency (RF) amplifier vacuum tubes and waveguides, where, under certain conditions, secondary electron emission in resonance with an alternating electromagnetic field leads to exponential electron multiplication, possibly damaging and even destroying the RF device.