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It may be prepared via the Schiemann reaction, in which a 4-aminobenzoic acid, protected as the ethyl ester, is diazotised and then fluoride introduced using tetrafluoroborate. Hydrolysis of the ester converts it back to the free acid. [2] 4-Fluorobenzoic acid has been observed to form by the aerobic biotransformation of 4-fluorocinnamic acid. [3]
4-Fluorobenzoic acid (para) This page was last edited on 9 February 2024, at 22:58 (UTC). Text is available under the Creative Commons Attribution ...
Pages in category "4-Fluorophenyl compounds" The following 200 pages are in this category, out of approximately 203 total. This list may not reflect recent changes .
The traditional Balz–Schiemann reaction employs HBF 4 and involves isolation of the diazonium salt. Both aspects can be profitably modified. Other counterions have been used in place of tetrafluoroborates, such as hexafluorophosphates (PF 6 −) and hexafluoroantimonates (SbF 6 −) with improved yields for some substrates.
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Benzoic acid is a constituent of Whitfield's ointment which is used for the treatment of fungal skin diseases such as ringworm and athlete's foot. [ 28 ] [ 29 ] As the principal component of gum benzoin , benzoic acid is also a major ingredient in both tincture of benzoin and Friar's balsam.
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