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The zero-point energy is inversely proportional to the square root of the mass of the vibrating hydrogen atom, and will therefore be smaller for a D–X bond that for an H–X bond. An example is a hydrogen atom abstraction reaction R' + H–R ⇌ R'–H + R with equilibrium constant K H , where R' and R are organic radicals such that R' forms ...
Mass fraction can also be expressed, with a denominator of 100, as percentage by mass (in commercial contexts often called percentage by weight, abbreviated wt.% or % w/w; see mass versus weight). It is one way of expressing the composition of a mixture in a dimensionless size ; mole fraction (percentage by moles , mol%) and volume fraction ...
Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
The ratio of the mass–action ratio to the equilibrium constant is often called the disequilibrium ratio, denoted by the symbol . ρ = Γ K e q {\displaystyle \rho ={\frac {\Gamma }{K_{eq}}}} and is a useful measure for indicating how far from equilibrium a given reaction is.
Note that this is also the result of an extrapolation to zero scattering angle. By acquiring data on concentration and scattering intensity, the Debye plot is constructed by plotting Kc/ΔR(θ) vs. concentration. The intercept of the fitted line gives the molecular mass, while the slope corresponds to the 2nd virial coefficient.
In reacting systems that include interphase mass transport, the first Damköhler number can be written as the ratio of the chemical reaction rate to the mass transfer rate D a I = reaction rate diffusive mass transfer rate {\displaystyle \mathrm {Da} _{\mathrm {I} }={\frac {\text{reaction rate}}{\text{diffusive mass transfer rate}}}}
The distribution constant (or partition ratio) (K D) is the equilibrium constant for the distribution of an analyte in two immiscible solvents. [1] [2] [3]In chromatography, for a particular solvent, it is equal to the ratio of its molar concentration in the stationary phase to its molar concentration in the mobile phase, also approximating the ratio of the solubility of the solvent in each phase.