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  2. Onsager reciprocal relations - Wikipedia

    en.wikipedia.org/wiki/Onsager_reciprocal_relations

    The basic thermodynamic potential is internal energy.In a simple fluid system, neglecting the effects of viscosity, the fundamental thermodynamic equation is written: = + where U is the internal energy, T is temperature, S is entropy, P is the hydrostatic pressure, V is the volume, is the chemical potential, and M mass.

  3. Hess's law - Wikipedia

    en.wikipedia.org/wiki/Hess's_law

    A representation of Hess's law (where H represents enthalpy) Hess's law of constant heat summation, also known simply as Hess's law, is a relationship in physical chemistry and thermodynamics [1] named after Germain Hess, a Swiss-born Russian chemist and physician who published it in 1840.

  4. Thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_equations

    The first and second law of thermodynamics are the most fundamental equations of thermodynamics. They may be combined into what is known as fundamental thermodynamic relation which describes all of the changes of thermodynamic state functions of a system of uniform temperature and pressure.

  5. Chemical thermodynamics - Wikipedia

    en.wikipedia.org/wiki/Chemical_thermodynamics

    The second was the 1933 book Modern Thermodynamics by the methods of Willard Gibbs written by E. A. Guggenheim. In this manner, Lewis, Randall, and Guggenheim are considered as the founders of modern chemical thermodynamics because of the major contribution of these two books in unifying the application of thermodynamics to chemistry. [1]

  6. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    [11] Assume two products B and C form in a reaction: a A + d D → b B, a A + d D → c C. In this case, K eq can be defined as ratio of B to C rather than the equilibrium constant. When ⁠ B / C ⁠ > 1, B is the favored product, and the data on the Van 't Hoff plot will be in the positive region.

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  8. Thermodynamics and an Introduction to Thermostatistics

    en.wikipedia.org/wiki/Thermodynamics_and_an...

    The first part of the book starts by presenting the problem thermodynamics is trying to solve, and provides the postulates on which thermodynamics is founded. It then develops upon this foundation to discuss reversible processes, heat engines, thermodynamics potentials, Maxwell's relations, stability of thermodynamics systems, and first-order phase transitions.

  9. Maxwell relations - Wikipedia

    en.wikipedia.org/wiki/Maxwell_relations

    The structure of Maxwell relations is a statement of equality among the second derivatives for continuous functions. It follows directly from the fact that the order of differentiation of an analytic function of two variables is irrelevant (Schwarz theorem).

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