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In some cases crystals do not form quickly and the solution remains supersaturated after cooling. This is because there is a thermodynamic barrier to the formation of a crystal in a liquid medium. Commonly this is overcome by adding a tiny crystal of the solute compound to the supersaturated solution, a process known as "seeding".
An example would be the synthesis of Cr 3+ tetraphenylporphyrin chloride: water is added to the dimethylformamide (DMF) solution in which the reaction occurred, and the product precipitates. [10] Precipitation is useful in purifying many other products: e.g. , crude bmim -Cl is taken up in acetonitrile , and dropped into ethyl acetate , where ...
A supersaturated solution of sodium acetate in water is supplied with a device to initiate crystallization, a process that releases substantial heat. Solubility from CRC Handbook Sodium acetate trihydrate crystals melt at 58–58.4 °C (136.4–137.1 °F), [ 12 ] [ 13 ] and the liquid sodium acetate dissolves in the released water of ...
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
A solvent dissolves a solute, resulting in a solution Ethyl acetate, a nail polish solvent. [1] A solvent (from the Latin solvÅ, "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid.
A saturated compound is a chemical compound (or ion) that resists addition reactions, such as hydrogenation, oxidative addition, and binding of a Lewis base.The term is used in many contexts and classes of chemical compounds.
The formation of a supersaturated solution does not guarantee crystal formation, and often a seed crystal or scratching the glass is required to form nucleation sites. A typical laboratory technique for crystal formation is to dissolve the solid in a solution in which it is partially soluble, usually at high temperatures to obtain supersaturation.
Saturation of a solute in a solution, as related to the solute's maximum solubility at equilibrium Supersaturation, where the concentration of a solute exceeds its maximum solubility at equilibrium; Undersaturation, where the concentration of a solute is less than its maximum solubility at equilibrium